The Journal of organic chemistry

An Improved Bouveault− Blanc Ester Reduction with Stabilized Alkali Metals

BS Bodnar, PF Vogt

文献索引：Bodnar, Brian S.; Vogt, Paul F. Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2598 - 2600

被引用次数: 38

摘要

Significantly improved Bouveault− Blanc conditions for ester reduction have been developed using sodium in silica gel (Na-SG), a free-flowing powder that can be easily handled in the open atmosphere. Primary alcohols were prepared in excellent yield from a variety of aliphatic esters under mild reaction conditions. The chemistry presented here is far safer than the classic Bouveault− Blanc reduction and is competitive with more modern ...

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