Inorganic chemistry

New pathways for chlorine dioxide decomposition in basic solution

IN Odeh, JS Francisco, DW Margerum

文献索引：Odeh, Ihab N.; Francisco, Joseph S.; Margerum, Dale W. Inorganic Chemistry, 2002 , vol. 41, # 24 p. 6500 - 6506

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被引用次数: 31

摘要

The decomposition of ClO2 in basic solution proceeds by three concurrent pathways. One pathway forms ClO2-and O2 (pathway 2) and is of greater importance at low ClO2 concentrations. The other two pathways (pathways 1 and 3) form equimolar levels of ClO2- and ClO3-. All pathways exhibit first-order dependence in OH-but have variable order in ClO2. The three pathways are proposed to proceed by base-assisted electron-transfer ...