Inorganic chemistry

Chlorine dioxide reduction by aqueous iron (II) through outer-sphere and inner-sphere electron-transfer pathways

L Wang, IN Odeh, DW Margerum

文献索引：Wang, Lu; Odeh, Ihab N.; Margerum, Dale W. Inorganic Chemistry, 2004 , vol. 43, # 23 p. 7545 - 7551

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被引用次数: 14

摘要

Chlorine dioxide reduction to chlorite by Fe (aq) 2+ proceeds via both outer-sphere and inner-sphere electron-transfer pathways. The outer-sphere path is dominant (86%). The inner-sphere pathway (14%) proceeds through the formation of an inner-sphere (FeIII (ClO2- )(H2O) 5) 2+ complex.