Inorganic chemistry

Kinetics and mechanism of catalytic decomposition and oxidation of chlorine dioxide by the hypochlorite ion

V Csordás, B Bubnis, I Fábián, G Gordon

文献索引：Csordas; Bubnis; Fabian; Gordon Inorganic Chemistry, 2001 , vol. 40, # 8 p. 1833 - 1836

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被引用次数: 30

摘要

A uniform rate law is applicable for the oxidation of chlorine dioxide by the hypochlorite ion in the entire neutral to alkaline pH range. At the same time, there is a changeover in the stoichiometry as a function of pH. A detailed mechanism is postulated that provides appropriate interpretation of the kinetic and stoichiometric results.