The Journal of organic chemistry

Carbamoylation of aryl halides by molybdenum or tungsten carbonyl amine complexes

W Ren, M Yamane

文献索引：Ren, Wei; Yamane, Motoki Journal of Organic Chemistry, 2010 , vol. 75, # 9 p. 3017 - 3020

被引用次数: 31

摘要

When aryl halide is treated with molybdenum carbonyl amine complex in the presence of base, carbamoylation proceeds to give amide in good yield. The proposed mechanism involves oxidative addition of aryl halide to molybdenum (0) complex, migratory insertion to

~97%

~78%

~89%

~49%

~40%

~75%

~97%

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