The Journal of organic chemistry

Carbamoylation of aryl halides by molybdenum or tungsten carbonyl amine complexes

W Ren, M Yamane

Index: Ren, Wei; Yamane, Motoki Journal of Organic Chemistry, 2010 , vol. 75, # 9 p. 3017 - 3020

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Citation Number: 31

Abstract

When aryl halide is treated with molybdenum carbonyl amine complex in the presence of base, carbamoylation proceeds to give amide in good yield. The proposed mechanism involves oxidative addition of aryl halide to molybdenum (0) complex, migratory insertion to

~97%

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