Regioselective radical arylation of anilines with arylhydrazines

…, J Scheumann, MR Heinrich

文献索引：Jasch, Hannelore; Hoefling, Sarah B.; Heinrich, Markus R. Journal of Organic Chemistry, 2012 , vol. 77, # 3 p. 1520 - 1532

全文：HTML全文

被引用次数: 40

摘要

Substituted 2-aminobiphenyls have been prepared from arylhydrazines and anilines via radical arylation reactions under simple oxidative conditions. The strong directing effect of the free and unprotonated amino functionality leads to high regioselectivities, and anilines have been shown to be significantly better aryl radical acceptors than nitrobenzenes or phenyl ethers. The methodology is also applicable to phenols, which react best as ...

~49%

查看详情

查看详情

查看详情

查看详情

~60%

查看详情

~42%

查看详情

查看详情

查看详情

查看详情

查看详情

查看详情

查看详情

~59%

查看详情

查看详情

查看详情

查看详情

查看详情

~63%

查看详情

~65%

查看详情

查看详情

查看详情

查看详情

查看详情

~77%

查看详情

查看详情

Synthesis of Monocarbenepalladium (0) Complexes and Their Ca...

[Selvakumar, Kumaravel; Zapf, Alexander; Spannenberg, Anke; Beller, Matthias Chemistry - A European Journal, 2002 , vol. 8, # 17 p. 3901 - 3906]

Enantioselective synthesis and enhanced circularly polarized...

[Zhang, Yu; Yang, Xinye; Yao, Qizheng; Ma, Dawei Organic Letters, 2012 , vol. 14, # 12 p. 3056 - 3059]

Photoinduced Intramolecular Electron Transfer in p-Polypheny...

[Foley, Michael J.; Singer, Lawrence A. Journal of Physical Chemistry, 1994 , vol. 98, # 26 p. 6430 - 6435]