The Journal of Physical Chemistry

Photoinduced Intramolecular Electron Transfer in p-Polyphenylamines and 1-(p-(N, N-Dialkylamino)-p-polyphenyl) naphthalenes

MJ Foley, LA Singer

文献索引：Foley, Michael J.; Singer, Lawrence A. Journal of Physical Chemistry, 1994 , vol. 98, # 26 p. 6430 - 6435

全文：HTML全文

被引用次数: 14

摘要

Photoinduced intramolecular electron transfer in two series of aromatic amines of the type aryl-(C6H,),,-NR2, where aryl is phenyl and 1-naphthyl and n= 1-3, has been studied. From the solvatochromic behavior of the fluorescences from these compounds, excited-state dipole moments ranging from 10.9 to 29.9 D have been measured, suggesting that the emissions occur from charge-transfer states, except in 4-(N, N-diethylamino)-biphenyl ( ...