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N-甲基环己胺

N-甲基环己胺用途

【用途一】
用作医药及染料的中间体
【用途二】
药物及染料中间体。用作药物盐酸溴已胺的中间体。

N-甲基环己胺名称

[ CAS 号 ]:
100-60-7

[ 中文名 ]:
N-甲基环己胺

[ 英文名 ]:
N-Methylcyclohexanamine

[中文别名 ]:

[英文别名 ]:

L6TJ AM1
N-Methylcyclohexanamine
MFCD00003832
N-Cyclohexylmethylamine
Cyclohexanamine, N-methyl-
N-Methylcyclohexylamine
EINECS 202-869-3

N-甲基环己胺物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
146.5±8.0 °C at 760 mmHg

[ 熔点 ]:
−9-−7 °C(lit.)

[ 分子式 ]:
C₇H₁₅N

[ 分子量 ]:
113.201

[ 闪点 ]:
29.4±0.0 °C

[ 精确质量 ]:
113.120445

[ PSA ]:
12.03000

[ LogP ]:
1.63

[ 外观性状 ]:
透明无色液体

[ 蒸汽密度 ]:
4 (vs air)

[ 蒸汽压 ]:
4.6±0.3 mmHg at 25°C

[ 折射率 ]:
1.451

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
5.4 g/100 mL (20 ºC)

N-甲基环己胺MSDS

N-甲基环己胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GX1529000

CHEMICAL NAME :: Cyclohexylamine, N-methyl-

CAS REGISTRY NUMBER :: 100-60-7

BEILSTEIN REFERENCE NO. :: 1523664

LAST UPDATED :: 199709

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C7-H15-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor Behavioral - ataxia

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,388,1969

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Skin and Appendages - corrosive (after topical exposure)

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,388,1969

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 7000 mg/m3/1H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,388,1969 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1402 No. of Facilities: 426 (estimated) No. of Industries: 5 No. of Occupations: 6 No. of Employees: 4190 (estimated)

N-甲基环己胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302 + H312-H314-H331

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R10;R20/21/22;R35

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2734 8/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
GX1529000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
29213099

N-甲基环己胺合成路线

N-甲基环己胺上下游产品

N-甲基环己胺上游产品

N-甲基环己胺下游产品

N-甲基环己胺制备

1.以环己胺为原料制得。

2.由环己酮与甲胺反应而得。将铝片浸泡在甲醇中，再加氯化高汞，继续浸泡2h，升温不超过55℃，除去浸泡液。向上述活化好的铝片加乙醇，在搅拌下滴加甲胺、环己酮的混合液，加热回流，放置过夜。加入10%氢氧化钠溶液碱化，用苯提取两次，经水洗后进行蒸馏，回收苯后即馏出N-甲基环己胺。收率约80%。

N-甲基环己胺海关

[ 海关编码 ]: 2921300090

[ 中文概述 ]:
2921300090 其他环（烷，烯，萜烯）单胺或多胺（包括其衍生物及它们的盐）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

N-甲基环己胺文献

Corrosion inhibition of carbon steel in petroleum/water mixtures by N-containing compounds. Ashassi-Sorkhabi H and Nabavi-Amri AS.

Acta Chim. Slov. 47(4) , 507-518, (2000)

Ultrasonic Velocity, Viscosity, Density and Excess Properties of Ternary Mixture of N-Methylcyclohexylamine+ Benzene+ 1-Propanol. Vasantharani P, et al.

Asian J. Applied Sciences 2(2) , 169-176, (2009)

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