ETHYLMAGNESIUM BROMIDE

Modify Date: 2024-01-07 10:06:11

ETHYLMAGNESIUM BROMIDE Structure
ETHYLMAGNESIUM BROMIDE structure
Common Name ETHYLMAGNESIUM BROMIDE
CAS Number 925-90-6 Molecular Weight 133.27000
Density 1.02 g/mL at 25 °C Boiling Point 34.6°C
Molecular Formula C2H5BrMg Melting Point -116.3°C
MSDS Chinese Flash Point <−30 °F
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Names

Name Ethylmagnesium Bromide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.02 g/mL at 25 °C
Boiling Point 34.6°C
Melting Point -116.3°C
Molecular Formula C2H5BrMg
Molecular Weight 133.27000
Flash Point <−30 °F
Exact Mass 131.94300
LogP 1.81950
Storage condition water-free area

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H225-H250-H260-H314
Supplemental HS May form explosive peroxides., Reacts violently with water.
Precautionary Statements P210-P222-P223-P231 + P232-P370 + P378-P422
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F+:Extremelyflammable;Xn:Harmful;C:Corrosive;
Risk Phrases R12;R15;R19;R22;R34
Safety Phrases S16-S26-S36/37/39-S43-S45-S7/8-S27
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
Packaging Group I
Hazard Class 4.3
HS Code 2931900090

 Synthetic Route

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ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

CAS#:925-90-6

Literature: US2008/242862 A1, ; Page/Page column 20 ; US 20080242862 A1

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ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

CAS#:925-90-6

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 60, # 6 p. 1219 - 1225,1087 - 1092

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ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

CAS#:925-90-6

Literature: Advanced Synthesis and Catalysis, , vol. 352, # 11-12 p. 2023 - 2031

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ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

CAS#:925-90-6

Detail
Literature: Chemische Berichte, , vol. 123, # 7 p. 1507 - 1515

~11%

Detail
Literature: Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 193 - 206

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Detail
Literature: Chemische Berichte, , vol. 123, # 7 p. 1507 - 1515

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ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

CAS#:925-90-6

Literature: Journal of the American Chemical Society, , vol. 61, p. 731,734

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Detail
Literature: Chemische Berichte, , vol. 123, # 7 p. 1507 - 1515

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles7

More Articles
New reagent system for attaining high regio- and stereoselectivities in allylic displacement of 4-cyclopentene-1,3-diol monoacetate with aryl- and alkenylmagnesium bromides.

Org. Lett. 7(2) , 183-6, (2005)

[Reaction: see text] Low regioselectivity of RMgBr (R = aryl, alkenyl) in the CuCN-catalyzed reaction with 4-cyclopentene-1,3-diol monoacetate is improved by addition of LiCl or MgCl2 to a similar ext...

Rhodococcus opacus strain PD630 as a new source of high-value single-cell oil? Isolation and characterization of triacylglycerols and other storage lipids.

Microbiology 146 ( Pt 5) , 1143-9, (2000)

The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for ...

Studies of the formation of all-carbon quaternary centres, en route to lyngbyatoxin A. A comparison of phenyl and 7-substituted indole systems.

Org. Biomol. Chem. 2(10) , 1447-55, (2004)

Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carb...

 Synonyms

ethylmagnesium bromide
MFCD00000043
EINECS 213-127-3
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