(2,3-Dihydrobenzofuran-2-yl)methanol

Modify Date: 2024-01-02 11:13:06

(2,3-Dihydrobenzofuran-2-yl)methanol Structure
(2,3-Dihydrobenzofuran-2-yl)methanol structure
Common Name (2,3-Dihydrobenzofuran-2-yl)methanol
CAS Number 66158-96-1 Molecular Weight 150.17400
Density 1.172g/cm3 Boiling Point 120-122
Molecular Formula C9H10O2 Melting Point N/A
MSDS N/A Flash Point 125.639ºC

 Names

Name (2,3-Dihydrobenzofuran-2-yl)methanol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.172g/cm3
Boiling Point 120-122
Molecular Formula C9H10O2
Molecular Weight 150.17400
Flash Point 125.639ºC
Exact Mass 150.06800
PSA 29.46000
LogP 0.98240
Index of Refraction 1.564
Storage condition 2-8°C

 MSDS

Name: 2 3-Dihydro-1-benzofuran-2-ylmethanol 90+% Material Safety Data Sheet
Synonym:
CAS: 66158-96-1
Section 1 - Chemical Product MSDS Name:2 3-Dihydro-1-benzofuran-2-ylmethanol 90+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
66158-96-1 2,3-Dihydro-1-benzofuran-2-ylmethanol 90%+ unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 66158-96-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid or liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H10O2
Molecular Weight: 150.18

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 66158-96-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3-Dihydro-1-benzofuran-2-ylmethanol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 66158-96-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 66158-96-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 66158-96-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S24/25
HS Code 2932999099

 Synthetic Route

~72%

(2,3-Dihydrobenzofuran-2-yl)methanol Structure

(2,3-Dihydroben...

CAS#:66158-96-1

Literature: Hamamoto, Hiromi; Suzuki, Yachiyo; Takahashi, Hideyo; Ikegami, Shiro Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2685 - 2689

~43%

(2,3-Dihydrobenzofuran-2-yl)methanol Structure

(2,3-Dihydroben...

CAS#:66158-96-1

Literature: European Journal of Organic Chemistry, , # 8 p. 1557 - 1569

~%

(2,3-Dihydrobenzofuran-2-yl)methanol Structure

(2,3-Dihydroben...

CAS#:66158-96-1

Literature: Journal of Organic Chemistry, , vol. 24, p. 11197,1199 Zhurnal Obshchei Khimii, , vol. 24, p. 807,810; engl. Ausg. S. 809, 811

~%

(2,3-Dihydrobenzofuran-2-yl)methanol Structure

(2,3-Dihydroben...

CAS#:66158-96-1

Literature: Synlett, , # 6 p. 942 - 946

~%

(2,3-Dihydrobenzofuran-2-yl)methanol Structure

(2,3-Dihydroben...

CAS#:66158-96-1

Literature: Journal of Organic Chemistry, , vol. 24, p. 1197

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

2,3-dihydro-1-benzofuran-2-ylmethanol
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