Amyl Chloroformate

Modify Date: 2024-01-05 16:55:51

Amyl Chloroformate Structure
Amyl Chloroformate structure
Common Name Amyl Chloroformate
CAS Number 638-41-5 Molecular Weight 150.603
Density 1.1±0.1 g/cm3 Boiling Point 164.9±9.0 °C at 760 mmHg
Molecular Formula C6H11ClO2 Melting Point N/A
MSDS USA Flash Point 47.7±11.9 °C

 Names

Name Pentyl chloroformate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 164.9±9.0 °C at 760 mmHg
Molecular Formula C6H11ClO2
Molecular Weight 150.603
Flash Point 47.7±11.9 °C
Exact Mass 150.044754
PSA 26.30000
LogP 3.03
Vapour Pressure 1.9±0.3 mmHg at 25°C
Index of Refraction 1.426
Storage condition Refrigerator

 MSDS

Amyl Chloroformate Revision number: 1
SAFETY DATA SHEET

Section1. BASE INFORMATION
Product name:Amyl Chloroformate

Revision number:1

Section2. HAZARDS IDENTIFICATION
Classification of the GHS
PHYSICAL HAZARDS
Flammable liquidsCategory 3
HEALTH HAZARDS
Acute toxicity (Inhalation)Category 2
Category 1B
Skin corrosion/irritation
Serious eye damage/eye irritationCategory 1
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements
Pictograms or hazard symbols
Signal wordDanger
Hazard statementFlammable liquid and vapour
Fatal if inhaled
Causes severe skin burns and eye damage
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
[Prevention]
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
measures against ignition by the static discharge and the spark.
Do not breathe.
Use only outdoors or in a well-ventilated area.
Wash hands thoroughly after handling.
Wear respiratory protection.
Wear protective gloves/eye protection/face protection.
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor/physician.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
Wash contaminated clothing before reuse.
Immediately call a POISON CENTER or doctor/physician.
Amyl Chloroformate

Section2. HAZARDS IDENTIFICATION
[Storage]Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
[Disposal]Dispose of contents/container through a waste management company authorized by
the local government

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Component(s):Amyl Chloroformate
>97.0%(GC)(T)
Percent:
CAS Number:638-41-5
Chloroformic Acid Amyl Ester , Chloroformic Acid Pentyl Ester , Pentyl Chloroformate
Synonyms:
Chemical Formula:C6H11ClO2

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. Immediately call a POISON CENTER or doctor/physician.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.Immediately call a POISON CENTER or
doctor/physician.
Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
Ingestion:
induce vomiting.
Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, carbon dioxide.
media:
Extinguishing media not to Water
be used:
Specific hazards:Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
spraying with water but NO direct contact with water. Eliminate all ignition sources if
safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use extra personal protective equipment (self-contained breathing apparatus). Keep
protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an
containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding.
up: Adhered or collected material should be promptly disposed of, in accordance with
appropriate laws and regulations.
Prevention of secondary Do not allow contact with water. Remove all sources of ignition. Fire-extinguishing
devices should be prepared in case of a fire. Use spark-proof tools and explosion-
hazards:
proof equipment.

Section7. HANDLING AND STORAGE
Handling
Amyl Chloroformate

Section7. HANDLING AND STORAGE
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapor or mist. Keep away from heat/sparks/open flame/hot
surfaces. -No smoking. Take measures to prevent the build up of electrostatic
charge. Use explosion-proof equipment. Wash hands and face thoroughly after
handling.
Use a closed system if possible. Use a ventilation, local exhaust if vapor or aerosol
will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
May develop pressure. Open carefully.
Storage
Storage conditions:Keep container tightly closed. Store in an explosion-poof refregerator.
Store under inert gas.
Protect from moisture.
Store locked up.
Store away from incompatible materials such as oxidizing agents.
Packaging material:Law is followed.

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Install a closed system or local exhaust. Also install safety shower and eye bath.
Engineering controls:
Personal protective equipment
Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
air respirator, etc. Use respirators approved under appropriate government standards
and follow local and national regulations.
Hand protection:Impervious gloves.
Eye protection:Safety goggles. A face-shield, if the situation requires.
Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Physical state (20°C):
Form:clear
Color:Colorless - Almost colorless
No data available
Odor:
pH: No data available
Melting point/freezing point:No data available
Boiling Point/Range:161 °C
No data available
Flash Point:
Explosive limits
Lower:No data available
Upper:No data available
Density:1.03
Solubility:No data available

Section10. STABILITY AND REACTIVITY
Stable under proper conditions.
Stability:
Reactivity:Decomposes in contact with water and liberates toxic gases.
Conditions to avoid:Heat-sensitive, Moisture-sensitive
Incompartible materials: oxidizing agents, bases, water
Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride
Products:

Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Amyl Chloroformate

Section11. TOXICOLOGICAL INFORMATION
Carcinogenicity:
No data available
IARC =
NTP =No data available
No data available
Reproductive toxicity:

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
Crustacea:No data available
Algae:No data available
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobillity in soil
log Pow:No data available
Soil adsorption (Koc):No data available
Henry's LawNo data available
constant(PaM3/mol):

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:6.1: Toxic substance.
Subsidiary risk:8: Corrosive.
UN-No:3277
Proper shipping name:Chloroformates, toxic, corrosive, n.o.s.
Packing group:II

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26,
2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes C
Risk Phrases R10
Safety Phrases S26-S36-S45
RIDADR 3277
Hazard Class 6.1
HS Code 2915900090

 Synthetic Route

~83%

Amyl Chloroformate Structure

Amyl Chloroformate

CAS#:638-41-5

Literature: Shi, Haibo; Hu, Weixiao; Sun, Yaquan Journal of Chemical Research, 2004 , # 10 p. 708 - 709

~%

Amyl Chloroformate Structure

Amyl Chloroformate

CAS#:638-41-5

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 22, # 12 p. 2278 - 2286 Zhurnal Organicheskoi Khimii, , vol. 22, # 12 p. 2540 - 2548

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Synonyms

Pentylchlorocarbonat
Chloroformic acid amyl ester
Formic acid, chloro-, pentyl ester
Pentyl chloridocarbonate
n-Pentyl chloroformate
Carbonochloridic acid, pentyl ester
Amyl Chloroformate
Pentyl carbonochloridate
Formic acid, chloro-, pentyl ester (8CI)
EINECS 211-336-4
MFCD00058933
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