bis(3-aminopropyl)amine

Modify Date: 2024-01-04 21:51:23

bis(3-aminopropyl)amine Structure
bis(3-aminopropyl)amine structure
Common Name bis(3-aminopropyl)amine
CAS Number 56-18-8 Molecular Weight 131.219
Density 0.9±0.1 g/cm3 Boiling Point 242.1±0.0 °C at 760 mmHg
Molecular Formula C6H17N3 Melting Point −14 °C(lit.)
MSDS Chinese USA Flash Point 118.3±0.0 °C
Symbol GHS05 GHS06 GHS08
GHS05, GHS06, GHS08
Signal Word Danger

 Names

Name bis(3-aminopropyl)amine
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 242.1±0.0 °C at 760 mmHg
Melting Point −14 °C(lit.)
Molecular Formula C6H17N3
Molecular Weight 131.219
Flash Point 118.3±0.0 °C
Exact Mass 131.142242
PSA 64.07000
LogP -1.14
Vapour Pressure 0.0±0.4 mmHg at 25°C
Index of Refraction 1.476
Stability Air and light sensitive. Combustible. Incompatible with oxidizing agents.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JL9450000
CHEMICAL NAME :
Dipropylamine, 3,3'-diamino-
CAS REGISTRY NUMBER :
56-18-8
BEILSTEIN REFERENCE NO. :
1071254
LAST UPDATED :
199710
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C6-H17-N3
MOLECULAR WEIGHT :
131.26
WISWESSER LINE NOTATION :
Z3M3Z

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/13/1968
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/13/1968 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
738 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
435 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
210 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
110 uL/kg
TOXIC EFFECTS :
Skin and Appendages - primary irritation (after topical exposure)
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/13/1968
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
258 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T0646 No. of Facilities: 520 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 4161 (estimated) No. of Female Employees: 1560 (estimated)

 Safety Information

Symbol GHS05 GHS06 GHS08
GHS05, GHS06, GHS08
Signal Word Danger
Hazard Statements H302-H311-H314-H317-H330-H341-H373
Precautionary Statements P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233
Target Organs thymus
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T+:Verytoxic;
Risk Phrases R22;R24;R26;R35;R43
Safety Phrases S26-S28-S36/37/39-S45
RIDADR UN 2269 8/PG 3
WGK Germany 2
RTECS JL9450000
Packaging Group III
Hazard Class 8

 Synthetic Route

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 Synonyms

N-(3-Aminopropyl)-1,3-propanediamine
bis(3-aminopropyl)amine
DIPROPYLENETRIAMINE
bis-(3-amino-propyl)amine
N-(3-AMINOPROPYL)PROPANE-1,3-DIAMINE
n,n-di(3-aminopropyl)amine
1,3-Propanediamine, N-(3-aminopropyl)-
N'-(3-aminopropyl)propane-1,3-diamine
1,3-Propanediamine, N- (3-aminopropyl)-
EINECS 200-261-2
MFCD00008214