2-Bromobenzamide

Modify Date: 2025-09-04 20:12:13

2-Bromobenzamide Structure
2-Bromobenzamide structure
 Common Name 2-Bromobenzamide
CAS Number 4001-73-4 Molecular Weight 200.033
Density 1.6±0.1 g/cm3 Boiling Point 298.0±23.0 °C at 760 mmHg
Molecular Formula C7H6BrNO Melting Point 160-162 °C(lit.)
MSDS USA Flash Point 134.0±22.6 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 2-Bromobenzamide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 298.0±23.0 °C at 760 mmHg
Melting Point 160-162 °C(lit.)
Molecular Formula C7H6BrNO
Molecular Weight 200.033
Flash Point 134.0±22.6 °C
Exact Mass 198.963272
PSA 43.09000
LogP 0.73
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.606
InChIKey NHNAEZDWNCRWRW-UHFFFAOYSA-N
SMILES NC(=O)c1ccccc1Br

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2924299090

 Synthetic Route

2-Bromobenzonitrile structure

2-Bromobenzonitrile

CAS#:2042-37-7

~90%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Kang, Dahye; Lee, Jinwoo; Lee, Hee-Yoon Organic Syntheses, 2012 , vol. 89, p. 66 - 72
2-Bromobenzaldoxime structure

2-Bromobenzaldoxime

CAS#:34158-72-0

~91%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Kim, Min; Lee, Jinwoo; Lee, Hee-Yoon; Chang, Sukbok Advanced Synthesis and Catalysis, 2009 , vol. 351, # 11-12 p. 1807 - 1812
Methyl 2-bromobenzoate structure

Methyl 2-bromob...

CAS#:610-94-6

~21%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Willis, Michael C.; Snell, Robert H.; Fletcher, Anthony J.; Woodward, Robert L. Organic Letters, 2006 , vol. 8, # 22 p. 5089 - 5091
2-Bromobenzaldehyde structure

2-Bromobenzaldehyde

CAS#:6630-33-7

~77%

2-Bromobenzonitrile structure

2-Bromobenzonitrile

CAS#:2042-37-7

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Garcia-Alvarez, Rocio; Diaz-Alvarez, Alba E.; Crochet, Pascale; Cadierno, Victorio RSC Advances, 2013 , vol. 3, # 17 p. 5889 - 5894
Bromobenzene structure

Bromobenzene

CAS#:108-86-1

N/A structure

N/A

CAS#:127099-85-8

~%

Benzamide, 4-bromo- structure

Benzamide, 4-bromo-

CAS#:698-67-9

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Naredla, Rajasekhar Reddy; Klumpp, Douglas A. Tetrahedron Letters, 2012 , vol. 53, # 35 p. 4779 - 4781
2-Bromostyrene structure

2-Bromostyrene

CAS#:2039-88-5

~45%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Sharif, Muhammad; Gong, Jin-Long; Langer, Peter; Beller, Matthias; Wu, Xiao-Feng Chemical Communications, 2014 , vol. 50, # 36 p. 4747 - 4750
1-(2-BROMOETHYL)PYRROLE structure

1-(2-BROMOETHYL...

CAS#:36081-66-0

~14%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

3-o-bromophenyl-4-phenyl-1,2,5-thiadiazole structure

3-o-bromophenyl...

CAS#:77989-10-7

2-(2-Bromophenyl)-4,6-diphenyl-1,3,5-triazine structure

2-(2-Bromopheny...

CAS#:77989-15-2

Literature: Mataka, Shuntaro; Hosoki, Akira; Takahashi, Kazufumi; Tashiro, Masashi Journal of Heterocyclic Chemistry, 1980 , vol. 17, p. 1681 - 1685
2-Bromobenzoyl chloride structure

2-Bromobenzoyl ...

CAS#:7154-66-7

~%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Schoepff Chemische Berichte, 1890 , vol. 23, p. 3437
2-Bromobenzoic acid structure

2-Bromobenzoic acid

CAS#:88-65-3

~%

2-Bromobenzamide Structure

2-Bromobenzamide

CAS#:4001-73-4

Literature: Schotten Chemische Berichte, 1888 , vol. 21, p. 2251

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles3

More Articles
Organometallic Palladium Complexes with a Water-Soluble Iminophosphorane Ligand as Potential Anticancer Agents.

Organometallics 31(16) , 5772-5781, (2012)

The synthesis and characterization of a new water-soluble iminophosphorane ligand TPA=N-C(O)-2BrC(6)H(4) (C,N-IM; TPA = 1,3,5-triaza-7-phosphaadamantane) 1 is reported. Oxidative addition of 1 to Pd(2...

Palladium-catalyzed annulation of arynes by o-halobenzamides: synthesis of phenanthridinones.

J. Org. Chem. 77(19) , 8648-56, (2012)

The palladium-catalyzed annulation of arynes by substituted o-halobenzamides produces N-substituted phenanthridinones in good yields. This methodology provides this important heterocyclic ring system ...

Microwave assisted copper-free Sonogashira coupling/5-exo-dig cycloisomerization domino reaction: access to 3-(phenylmethylene) isoindolin-1-ones and related heterocycles. Hellal M and Cuny GD.

Tetrahedron Lett. 52(42) , 5508-11, (2011)

 Synonyms

EINECS 223-650-9
MFCD00007969
ZVR BE
o-Bromobenzamide
Benzamide, 2-bromo-
2-Bromobenzamide
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