Methyl pentafluoropropanoate

Modify Date: 2024-01-02 17:20:43

Methyl pentafluoropropanoate Structure
Methyl pentafluoropropanoate structure
 Common Name Methyl pentafluoropropanoate
CAS Number 378-75-6 Molecular Weight 178.057
Density 1.4±0.1 g/cm3 Boiling Point 62.5±35.0 °C at 760 mmHg
Molecular Formula C4H3F5O2 Melting Point N/A
MSDS N/A Flash Point 5.6±0.0 °C

 Names

Name Methyl Perfluoropropionate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 62.5±35.0 °C at 760 mmHg
Molecular Formula C4H3F5O2
Molecular Weight 178.057
Flash Point 5.6±0.0 °C
Exact Mass 178.005325
PSA 26.30000
LogP 1.60
Vapour Pressure 177.5±0.1 mmHg at 25°C
Index of Refraction 1.295
Storage condition Flammables area

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UF6475500
CHEMICAL NAME :
Propionic acid, pentafluoro-, methyl ester
CAS REGISTRY NUMBER :
378-75-6
BEILSTEIN REFERENCE NO. :
1777501
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-H3-F5-O2
MOLECULAR WEIGHT :
178.07
WISWESSER LINE NOTATION :
FXFFXFFVO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(3),48,1974
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
23 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(3),48,1974
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(3),48,1974

 Safety Information

Hazard Codes F:Flammable;Xi:Irritant;
Risk Phrases R11;R36/37/38
Safety Phrases S16-S26-S37/39
RIDADR UN 3272 3/PG 2
WGK Germany 2
RTECS UF6475500
Packaging Group II
Hazard Class 3
HS Code 2915900090

 Synthetic Route

Methanol structure

Methanol

CAS#:67-56-1
Pentafluoropropanoic acid structure

Pentafluoroprop...

CAS#:422-64-0

~%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6
Literature: Moore,R.A.; Levine,R. Journal of Organic Chemistry, 1964 , vol. 29, p. 1439 - 1444
4-heptafluoropropoxytrifluoro-1,2-oxathietane 2,2-dioxide structure

4-heptafluoropr...

CAS#:62949-75-1

~%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6

Methyldifluor(fluorsulfonyl)acetat structure

Methyldifluor(f...

CAS#:680-15-9
Literature: Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.2, page 121 - 136
Sodium Methylate structure

Sodium Methylate

CAS#:124-41-4
3,3-Bis(trifluoromethyl)-2-fluoro-2-(pentafluoroethyl)oxirane structure

3,3-Bis(trifluo...

CAS#:788-67-0

~0%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6

Hexafluoroisopropyl methyl ether structure

Hexafluoroisopr...

CAS#:13171-18-1
Literature: Zapevalov, A. Ya.; Filyakova, T. I.; Kolenko, I. P.; Peschanskii, N. V.; Kodess, M. I. Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 11 p. 2066 - 2071 Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 11 p. 2267 - 2273
Tetrafluoroethylene structure

Tetrafluoroethylene

CAS#:116-14-3
methyl carbonofluoridate structure

methyl carbonof...

CAS#:1538-06-3

~%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6
Literature: Galimberti, Marco; Fontana, Giovanni; Resnati, Giuseppe; Navarrini, Walter Journal of Fluorine Chemistry, 2005 , vol. 126, # 11-12 p. 1578 - 1586
Methanol structure

Methanol

CAS#:67-56-1
4-heptafluoropropoxytrifluoro-1,2-oxathietane 2,2-dioxide structure

4-heptafluoropr...

CAS#:62949-75-1

~%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6
Literature: Krespan,C.G. et al. Journal of the American Chemical Society, 1977 , vol. 99, p. 1214 - 1217
Methanol structure

Methanol

CAS#:67-56-1
Perfluoro-2-methyl-2-pentene structure

Perfluoro-2-met...

CAS#:1584-03-8

~%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6

2H-Perfluoro(2-methylpentane) structure

2H-Perfluoro(2-...

CAS#:30320-28-6
Literature: Moldavskii; Bispen; Furin; Zhuzhgov Russian Journal of Applied Chemistry, 1996 , vol. 69, # 4 p. 575 - 582
Ethanol structure

Ethanol

CAS#:64-17-5
Pentafluoropropionyl fluoride structure

Pentafluoroprop...

CAS#:422-61-7
Dimethyl sulfate structure

Dimethyl sulfate

CAS#:77-78-1

~2%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6

Detail
Literature: Cheburkov, Yuri; Lillquist, Gerald J. Journal of Fluorine Chemistry, 2002 , vol. 118, # 1-2 p. 123 - 126
Methanol structure

Methanol

CAS#:67-56-1
3-Methoxypropanoic acid structure

3-Methoxypropan...

CAS#:2544-06-1

~%

Methyl pentafluoropropanoate Structure

Methyl pentaflu...

CAS#:378-75-6
Literature: Berenblit,V.V. et al. J. Appl. Chem. USSR (Engl. Transl.), 1974 , vol. 47, p. 2433 - 2435,2503 - 2505
sodium 2,3,3,3-tetrafluoro-2-methoxypropanoate structure

sodium 2,3,3,3-...

CAS#:123202-05-1
Sodium pentafluoropropanoate structure

Sodium pentaflu...

CAS#:378-77-8

~%

Tetrafluoroethylene structure

Tetrafluoroethylene

CAS#:116-14-3
Methyl trifluoroacetate structure

Methyl trifluor...

CAS#:431-47-0
Detail
Literature: Pellerite, Mark J. Journal of Fluorine Chemistry, 1990 , vol. 49, # 1 p. 43 - 66

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Synonyms

2,2,3,3,3-Pentafluoro-propionic acid methyl ester
EINECS 206-828-0
Methyl pentafluoropropanoate
Methyl Pentafluoropropionate
Methyl perfluoropropionate
methyl 2,2,3,3,3-pentafluoropropanoate
Propanoic acid, 2,2,3,3,3-pentafluoro-, methyl ester
Pentafluoropropanoic acid methyl ester
Pentafluoropropionic Acid Methyl Ester
Perfluoropropionic Acid Methyl Ester
MFCD00000430
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