Journal of fluorine chemistry

Perfluoroalcohols

Y Cheburkov, GJ Lillquist

Index: Cheburkov, Yuri; Lillquist, Gerald J. Journal of Fluorine Chemistry, 2002 , vol. 118, # 1-2 p. 123 - 126

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Citation Number: 7

Abstract

Perfluoroalcohols are not known as a general class of compounds [1] and [2]. The CF 2 OH and CFOH groups are unstable and decompose into hydrogen fluoride and perfluorinated carbonyl compounds. This is especially true for primary perfluoroalcohols, although secondary perfluorocyclobutanol with a fluorine atom directly attached to the carbon that also carries the hydroxyl, has been isolated [3]. ... We have found that perfluoroalcohols give adducts with triethylamine that are ...