1,1'-(1,3-Phenylene)bis(1H-pyrrole-2,5-dione)

Modify Date: 2025-08-21 07:22:45

1,1'-(1,3-Phenylene)bis(1H-pyrrole-2,5-dione) Structure
1,1'-(1,3-Phenylene)bis(1H-pyrrole-2,5-dione) structure
Common Name 1,1'-(1,3-Phenylene)bis(1H-pyrrole-2,5-dione)
CAS Number 3006-93-7 Molecular Weight 268.224
Density 1.6±0.1 g/cm3 Boiling Point 499.3±28.0 °C at 760 mmHg
Molecular Formula C14H8N2O4 Melting Point 198-201 °C(lit.)
MSDS Chinese USA Flash Point 250.7±16.4 °C
Symbol GHS06
GHS06
Signal Word Danger

 Names

Name N,N'-1,3-Phenylene bismaleimide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 499.3±28.0 °C at 760 mmHg
Melting Point 198-201 °C(lit.)
Molecular Formula C14H8N2O4
Molecular Weight 268.224
Flash Point 250.7±16.4 °C
Exact Mass 268.048401
PSA 74.76000
LogP -0.04
Vapour Pressure 0.0±1.3 mmHg at 25°C
Index of Refraction 1.704
InChIKey IPJGAEWUPXWFPL-UHFFFAOYSA-N
SMILES O=C1C=CC(=O)N1c1cccc(N2C(=O)C=CC2=O)c1
Water Solubility negligible soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ON6125000
CHEMICAL NAME :
Maleimide, N,N'-(m-phenylene)di-
CAS REGISTRY NUMBER :
3006-93-7
BEILSTEIN REFERENCE NO. :
0249503
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C14-H8-N2-O4
MOLECULAR WEIGHT :
268.24
WISWESSER LINE NOTATION :
T5VNVJ BR C- BT5VNVJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1370 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 40(11),109,1975
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
55 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0790-1023S
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,22,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 40(11),109,1975 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83308 No. of Facilities: 14 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 212 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83308 No. of Facilities: 195 (estimated) No. of Industries: 8 No. of Occupations: 8 No. of Employees: 5373 (estimated) No. of Female Employees: 2054 (estimated)

 Safety Information

Symbol GHS06
GHS06
Signal Word Danger
Hazard Statements H302-H311-H330
Precautionary Statements P260-P280-P284-P310
Personal Protective Equipment Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
Hazard Codes T+:Verytoxic;
Risk Phrases R22;R26;R36/37/38
Safety Phrases S27-S28-S36/37/39-S45-S38-S28A
RIDADR UN 2811 6.1/PG 2
WGK Germany 3
RTECS ON6125000
HS Code 2925190090

 Synthetic Route

~86%

1,1'-(1,3-Phenylene)bis(1H-pyrrole-2,5-dione) Structure

1,1'-(1,3-Pheny...

CAS#:3006-93-7

Literature: E. I. Du Pont de Nemours and Company Patent: US4154737 A1, 1979 ;

 Precursor & DownStream

Precursor  2

DownStream  0

 Customs

HS Code 2925190090
Summary 2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

N,N'-1,3-Phenylenebismaleimide
1H-Pyrrole-2,5-dione, 1,1'-(1,3-phenylene)bis-
1,3-bismaleimidobenzene
MFCD00022569
N,N'-1,3-Bismaleimidobenzene
N,N'-m-phenylenedimaleimide
N,N'-meta-phenylene-bis-maleimide
m-Dimaleimidobenzene
N,N'-(1,3-PHENYLENE)DIMALEIMIDE
hva2
1,1'-m-Phenylen-bis-pyrrol-2,5-dion
m-phdm
1,1'-(m-Phenylene)bis-1H-pyrrole-2,5-dione (9CI)
VANAX MBM
N,N'-1,3-Phenylenedimaleimide
1,1'-m-phenylene-bis-pyrrole-2,5-dione
1,1'-(1,3-Phenylene)bis(1H-pyrrole-2,5-dione)
EINECS 221-112-8
hva-2curingagent
1-[3-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)phenyl]-2,5-dihydro-1H-pyrrole-2,5-dione
1,3-dimaleimidobenzene
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