![]() JohnPhos structure
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Common Name | JohnPhos | ||
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CAS Number | 224311-51-7 | Molecular Weight | 298.40 | |
Density | 1 g/cm3 | Boiling Point | 405.5±24.0 °C at 760 mmHg | |
Molecular Formula | C20H27P | Melting Point | 86-88 °C(lit.) | |
MSDS | Chinese USA | Flash Point | 210.1±29.2 °C |
Use of JohnPhosJohnPhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
Name | ditert-butyl-(2-phenylphenyl)phosphane |
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Synonym | More Synonyms |
Description | JohnPhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
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Related Catalog |
Density | 1 g/cm3 |
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Boiling Point | 405.5±24.0 °C at 760 mmHg |
Melting Point | 86-88 °C(lit.) |
Molecular Formula | C20H27P |
Molecular Weight | 298.40 |
Flash Point | 210.1±29.2 °C |
Exact Mass | 298.185028 |
PSA | 13.59000 |
LogP | 6.78 |
Vapour Pressure | 0.0±0.9 mmHg at 25°C |
Water Solubility | Insoluble |
Hazard Statements | H413 |
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Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
Hazard Codes | Xn:Harmful; |
Risk Phrases | R22;R36/37/38 |
Safety Phrases | S36/37/39-S26-S22 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2902909090 |
~86% JohnPhos CAS#:224311-51-7 |
Literature: HOKKO CHEMICAL INDUSTRY CO. LTD. Patent: EP1473297 A1, 2004 ; Location in patent: Page 19 ; |
~56% JohnPhos CAS#:224311-51-7 |
Literature: Buchwald, Stephen L.; Huang, Xiaohua; Zim, Danilo Patent: US2004/171833 A1, 2004 ; |
~65% JohnPhos CAS#:224311-51-7 |
Literature: Nippon Chemical Industrial Co., Ltd. Patent: US2009/54690 A1, 2009 ; Location in patent: Page/Page column 6-7 ; |
~66% JohnPhos CAS#:224311-51-7 |
Literature: Wolfe, John P.; Singer, Robert A.; Yang, Bryant H.; Buchwald, Stephen L. Journal of the American Chemical Society, 1999 , vol. 121, # 41 p. 9550 - 9561 |
~% JohnPhos CAS#:224311-51-7 |
Literature: Chemical Communications, , vol. 50, # 17 p. 2193 - 2195 |
~% JohnPhos CAS#:224311-51-7 |
Literature: Chemical Communications, , vol. 50, # 17 p. 2193 - 2195 |
~% JohnPhos CAS#:224311-51-7 |
Literature: Chemical Communications, , vol. 50, # 17 p. 2193 - 2195 |
Precursor 8 | |
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DownStream 5 | |
HS Code | 2902909090 |
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Summary | 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0% |
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th... |
Biphenyl-2-yl(di-tert-butyl)phosphan |
(o-biphenyl)P(t-Bu)2 |
2-(DI-T-BUTYLPHOSPHINO)BIPHENYL |
biphenyl-2-yl-di-tert-butyl-phosphane |
(2-Biphenylyl)di-tert-butylphosphine |
biphenyl-2-yl-di-tert-butylphosphine |
2-(Di-tert-butylphosphino)biphenyl |
2-(di-tert-butyl-phosphino)biphenyl |
MFCD01862440 |
JohnPhos |
2-Biphenylyl[bis(2-methyl-2-propanyl)]phosphine |
(2-Biphenyl)di-tert-butylphosphine |
Biphenyl-2-yl(di-tert-butyl)phosphane |
P(t-Bu)2(2-biphenyl) |
Phosphine, [1,1'-biphenyl]-2-ylbis(1,1-dimethylethyl)- |
Biphenyl-2-yl(di-tert-butyl)phosphine |
[1,1'-biphenyl]-2-ylbis(1,1-dimethylethyl)phosphine |