JohnPhos structure
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Common Name | JohnPhos | ||
|---|---|---|---|---|
| CAS Number | 224311-51-7 | Molecular Weight | 298.40 | |
| Density | 1 g/cm3 | Boiling Point | 405.5±24.0 °C at 760 mmHg | |
| Molecular Formula | C20H27P | Melting Point | 86-88 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 210.1±29.2 °C | |
Use of JohnPhosJohnPhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
| Name | ditert-butyl-(2-phenylphenyl)phosphane |
|---|---|
| Synonym | More Synonyms |
| Description | JohnPhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
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| Related Catalog |
| Density | 1 g/cm3 |
|---|---|
| Boiling Point | 405.5±24.0 °C at 760 mmHg |
| Melting Point | 86-88 °C(lit.) |
| Molecular Formula | C20H27P |
| Molecular Weight | 298.40 |
| Flash Point | 210.1±29.2 °C |
| Exact Mass | 298.185028 |
| PSA | 13.59000 |
| LogP | 6.78 |
| Vapour Pressure | 0.0±0.9 mmHg at 25°C |
| Water Solubility | Insoluble |
| Hazard Statements | H413 |
|---|---|
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
| Hazard Codes | Xn:Harmful; |
| Risk Phrases | R22;R36/37/38 |
| Safety Phrases | S36/37/39-S26-S22 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 2902909090 |
|
~86%
JohnPhos CAS#:224311-51-7 |
| Literature: HOKKO CHEMICAL INDUSTRY CO. LTD. Patent: EP1473297 A1, 2004 ; Location in patent: Page 19 ; |
|
~56%
JohnPhos CAS#:224311-51-7 |
| Literature: Buchwald, Stephen L.; Huang, Xiaohua; Zim, Danilo Patent: US2004/171833 A1, 2004 ; |
|
~65%
JohnPhos CAS#:224311-51-7 |
| Literature: Nippon Chemical Industrial Co., Ltd. Patent: US2009/54690 A1, 2009 ; Location in patent: Page/Page column 6-7 ; |
|
~66%
JohnPhos CAS#:224311-51-7 |
| Literature: Wolfe, John P.; Singer, Robert A.; Yang, Bryant H.; Buchwald, Stephen L. Journal of the American Chemical Society, 1999 , vol. 121, # 41 p. 9550 - 9561 |
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~%
JohnPhos CAS#:224311-51-7 |
| Literature: Chemical Communications, , vol. 50, # 17 p. 2193 - 2195 |
|
~%
JohnPhos CAS#:224311-51-7 |
| Literature: Chemical Communications, , vol. 50, # 17 p. 2193 - 2195 |
|
~%
JohnPhos CAS#:224311-51-7 |
| Literature: Chemical Communications, , vol. 50, # 17 p. 2193 - 2195 |
| Precursor 8 | |
|---|---|
| DownStream 5 | |
| HS Code | 2902909090 |
|---|---|
| Summary | 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0% |
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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th... |
| Biphenyl-2-yl(di-tert-butyl)phosphan |
| (o-biphenyl)P(t-Bu)2 |
| 2-(DI-T-BUTYLPHOSPHINO)BIPHENYL |
| biphenyl-2-yl-di-tert-butyl-phosphane |
| (2-Biphenylyl)di-tert-butylphosphine |
| biphenyl-2-yl-di-tert-butylphosphine |
| 2-(Di-tert-butylphosphino)biphenyl |
| 2-(di-tert-butyl-phosphino)biphenyl |
| MFCD01862440 |
| JohnPhos |
| 2-Biphenylyl[bis(2-methyl-2-propanyl)]phosphine |
| (2-Biphenyl)di-tert-butylphosphine |
| Biphenyl-2-yl(di-tert-butyl)phosphane |
| P(t-Bu)2(2-biphenyl) |
| Phosphine, [1,1'-biphenyl]-2-ylbis(1,1-dimethylethyl)- |
| Biphenyl-2-yl(di-tert-butyl)phosphine |
| [1,1'-biphenyl]-2-ylbis(1,1-dimethylethyl)phosphine |