2-Acetoxyacetyl chloride

Modify Date: 2024-01-02 09:33:04

2-Acetoxyacetyl chloride Structure
2-Acetoxyacetyl chloride structure
Common Name 2-Acetoxyacetyl chloride
CAS Number 13831-31-7 Molecular Weight 136.534
Density 1.3±0.1 g/cm3 Boiling Point 163.7±0.0 °C at 760 mmHg
Molecular Formula C4H5ClO3 Melting Point N/A
MSDS USA Flash Point 71.1±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name Acetoxyacetyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 163.7±0.0 °C at 760 mmHg
Molecular Formula C4H5ClO3
Molecular Weight 136.534
Flash Point 71.1±0.0 °C
Exact Mass 135.992722
PSA 43.37000
LogP 0.56
Vapour Pressure 2.0±0.3 mmHg at 25°C
Index of Refraction 1.425
Storage condition water-free area

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H314-H335
Supplemental HS Reacts violently with water.
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R14;R34
Safety Phrases S23-S26-S27-S36/37/39-S45-S8
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 8
HS Code 2915390090

 Synthetic Route

~80%

2-Acetoxyacetyl chloride Structure

2-Acetoxyacetyl...

CAS#:13831-31-7

Literature: Zaugg, Harold E.; Kyncl, Jaroslav Journal of Medicinal Chemistry, 1983 , vol. 26, # 2 p. 214 - 217

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2-Acetoxyacetyl chloride Structure

2-Acetoxyacetyl...

CAS#:13831-31-7

Literature: Journal of the American Chemical Society, , vol. 76, p. 658,661

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2-Acetoxyacetyl chloride Structure

2-Acetoxyacetyl...

CAS#:13831-31-7

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 9, p. 2258 - 2261 Zhurnal Organicheskoi Khimii, , vol. 9, p. 2241 - 2245

 Customs

HS Code 2915390090
Summary 2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

 Articles2

More Articles
Entrapment and kinetic resolution of stabilized axial and equatorial conformers of spiro-β-lactams.

J. Org. Chem. 76(15) , 5999-6006, (2011)

The facile synthesis of the stabilized axial and equatorial conformers of spiro-β-lactams was achieved via entrapment of cyclohexanone imines (Schiff bases) with acetoxyacetyl chloride in a [2 + 2]-cy...

N-glycolylhydroxamic acids: an improved synthetic method and the in situ generation and intramolecular rearrangement of N-acetoxy-N-glycolyl-2-aminofluorene.

Chem. Res. Toxicol. 1(4) , 222-7, (1988)

A new and improved method for the synthesis of glycolylhydroxamic acids is described. The two-step method involves acylation of arylhydroxylamines with acetoxyacetyl chloride, followed by saponificati...

 Synonyms

MFCD00011535
(2-chloro-2-oxoethyl) acetate
2-Chloro-2-oxoethyl acetate
EINECS 237-542-4
2-Acetoxyacetyl chloride
Acetyl chloride, 2-(acetyloxy)-
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