(+)-3-Bromocamphor

Modify Date: 2024-01-05 18:55:27

(+)-3-Bromocamphor Structure
(+)-3-Bromocamphor structure
Common Name (+)-3-Bromocamphor
CAS Number 10293-06-8 Molecular Weight 231.130
Density 1.4±0.1 g/cm3 Boiling Point 245.6±23.0 °C at 760 mmHg
Molecular Formula C10H15BrO Melting Point 74-78ºC
MSDS Chinese USA Flash Point 35.8±9.9 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name endo-3-Bromo-D-camphor
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 245.6±23.0 °C at 760 mmHg
Melting Point 74-78ºC
Molecular Formula C10H15BrO
Molecular Weight 231.130
Flash Point 35.8±9.9 °C
Exact Mass 230.030624
PSA 17.07000
LogP 2.42
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.529

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ED6750000
CHEMICAL NAME :
2-Bornanone, 3-bromo-, (1R,3S,4S)-(+)-
CAS REGISTRY NUMBER :
10293-06-8
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C10-H15-Br-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,20,1953

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS ED6750000
HS Code 2914700090

 Synthetic Route

~79%

(+)-3-Bromocamphor Structure

(+)-3-Bromocamphor

CAS#:10293-06-8

Literature: Lewis, Frank W.; McCabe, Thomas C.; Grayson, David H. Tetrahedron, 2011 , vol. 67, # 39 p. 7517 - 7528

~%

(+)-3-Bromocamphor Structure

(+)-3-Bromocamphor

CAS#:10293-06-8

Literature: Journal of Chemical Research, Miniprint, , # 6 p. 2101 - 2147

 Customs

HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

 Articles4

More Articles
Camphor: a chiral starting material in natural product synthesis.

Nat. Prod. Rep. , 253, (1985)

J.H. Hutchinson, T. Money

Can. J. Chem. 65 , 1, (1987)

R.V. Stevens, D.S. Lawrence

Tetrahedron 41 , 93, (1985)

 Synonyms

(+)-3-Bromocamphor
MFCD00003744
(1R,3S,4S)-3-Bromo-1,7,7-trimethylbicyclo-[2.2.1]heptan-2-one
endo-(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(+)-Camphor Bromide
EINECS 233-652-1
Bicyclo[2.2.1]heptan-2-one, 3-bromo-1,7,7-trimethyl-, (1R)-