(+)-3-Bromocamphor
Names
[ CAS No. ]:
10293-06-8
[ Name ]:
(+)-3-Bromocamphor
[Synonym ]:
(+)-3-Bromocamphor
MFCD00003744
(1R,3S,4S)-3-Bromo-1,7,7-trimethylbicyclo-[2.2.1]heptan-2-one
endo-(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(+)-Camphor Bromide
EINECS 233-652-1
Bicyclo[2.2.1]heptan-2-one, 3-bromo-1,7,7-trimethyl-, (1R)-
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
245.6±23.0 °C at 760 mmHg
[ Melting Point ]:
74-78ºC
[ Molecular Formula ]:
C10H15BrO
[ Molecular Weight ]:
231.130
[ Flash Point ]:
35.8±9.9 °C
[ Exact Mass ]:
230.030624
[ PSA ]:
17.07000
[ LogP ]:
2.42
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.529
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- ED6750000
- CHEMICAL NAME :
- 2-Bornanone, 3-bromo-, (1R,3S,4S)-(+)-
- CAS REGISTRY NUMBER :
- 10293-06-8
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 1
- MOLECULAR FORMULA :
- C10-H15-Br-O
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,20,1953
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ RTECS ]:
ED6750000
[ HS Code ]:
2914700090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914700090
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
Articles
Nat. Prod. Rep. , 253, (1985)
J.H. Hutchinson, T. Money
Can. J. Chem. 65 , 1, (1987)
R.V. Stevens, D.S. Lawrence
Tetrahedron 41 , 93, (1985)