Benzoyl bromide
Names
[ CAS No. ]:
618-32-6
[ Name ]:
Benzoyl bromide
[Synonym ]:
EINECS 210-544-2
MFCD00000112
benzoyl bromide
Chemical & Physical Properties
[ Density]:
1.57 g/mL at 25 °C(lit.)
[ Boiling Point ]:
218-219 °C(lit.)
[ Melting Point ]:
-24 °C
[ Molecular Formula ]:
C7H5BrO
[ Molecular Weight ]:
185.01800
[ Flash Point ]:
90 °C
[ Exact Mass ]:
183.95200
[ PSA ]:
17.07000
[ LogP ]:
2.22170
[ Index of Refraction ]:
n20/D 1.589(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314-H335
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2916399090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2916399090
[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Langmuir 22(18) , 7499-506, (2006)
A study was carried out on the solvolysis reactions of different benzoyl halides in microemulsions of water/NH4DEHP/isooctane, where NH4DEHP is ammonium bis(2-ethylhexyl) phosphate. Because of the low...
Zinc triflate-benzoyl bromide: a versatile reagent for the conversion of ether into benzoate protecting groups and ether glycosides into glycosyl bromides.Carbohydr. Res. 338(5) , 447-9, (2003)
A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and ben...