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Benzoyl bromide

Names

[ CAS No. ]:
618-32-6

[ Name ]:
Benzoyl bromide

[Synonym ]:
EINECS 210-544-2
MFCD00000112
benzoyl bromide

Chemical & Physical Properties

[ Density]:
1.57 g/mL at 25 °C(lit.)

[ Boiling Point ]:
218-219 °C(lit.)

[ Melting Point ]:
-24 °C

[ Molecular Formula ]:
C7H5BrO

[ Molecular Weight ]:
185.01800

[ Flash Point ]:
90 °C

[ Exact Mass ]:
183.95200

[ PSA ]:
17.07000

[ LogP ]:
2.22170

[ Index of Refraction ]:
n20/D 1.589(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2916399090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Solvolysis of benzoyl halides in water/NH4DEHP/isooctane microemulsions.

Langmuir 22(18) , 7499-506, (2006)

A study was carried out on the solvolysis reactions of different benzoyl halides in microemulsions of water/NH4DEHP/isooctane, where NH4DEHP is ammonium bis(2-ethylhexyl) phosphate. Because of the low...

Zinc triflate-benzoyl bromide: a versatile reagent for the conversion of ether into benzoate protecting groups and ether glycosides into glycosyl bromides.

Carbohydr. Res. 338(5) , 447-9, (2003)

A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and ben...


More Articles


Related Compounds