Bis(dibenzylideneacetone)palladium

Names

[ CAS No. ]:
32005-36-0

[ Name ]:
Bis(dibenzylideneacetone)palladium

[Synonym ]:
(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one
1,4-Pentadien-3-one, 1,5-diphenyl-, (1E,4E)-, palladium salt (2:1)
Bis(dibenzylideneacetone) palladium(0)
(1E,4E)-1,5-Diphenyl-1,4-pentadien-3-one - palladium (2:1)
Bis(dibenzylideneacetone)palladium(0)
bis-(dibenzylideneacetone)palladium(0)
Palladium(0) bis(dibenzylideneacetone)
(1E,4E)-1,5-Diphenylpenta-1,4-dien-3-one - palladium (2:1)
PD(DBA)2
palladium bis(dibenzylideneacetone)
Bis(dibenzylideneacetone)palladium
MFCD00051942

Biological Activity

[Description]:

Bis(dibenzylideneacetone)palladium is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

[In Vitro]

氢化、异构化、羰基化、氧化、CC键形成。Bis(dibenzylideneacetone)palladium(0) 用作制备烯丙基取代的环戊二烯的试剂。它作为均相催化剂以及各种亲核试剂对乙酸烯丙酯的烷基化作用。此外，它还用于铃木反应。

Chemical & Physical Properties

[ Boiling Point ]:
400.7ºC at 760 mmHg

[ Melting Point ]:
150°C

[ Molecular Formula ]:
C₃₆H₄₂O₂Pd

[ Molecular Weight ]:
613.14

[ Flash Point ]:
176.1ºC

[ Exact Mass ]:
574.112427

[ PSA ]:
34.14000

[ LogP ]:
7.96460

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S22-S24/25-S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914399090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914399090

[ Summary ]:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Palladium-catalyzed, asymmetric Mizoroki-Heck reaction of benzylic electrophiles using phosphoramidites as chiral ligands.

J. Am. Chem. Soc. 134(29) , 11833-5, (2012)

We report herein the first examples of asymmetric Mizoroki-Heck reactions using benzyl electrophiles. A new phosphoramidite was identified to be an effective chiral ligand in the palladium-catalyzed r...

Controlling olefin isomerization in the heck reaction with neopentyl phosphine ligands.

J. Org. Chem. , (2014)

The use of neopentyl phosphine ligands was examined in the coupling of aryl bromides with alkenes. Di-tert-butylneopentylphosphine (DTBNpP) was found to promote Heck couplings with aryl bromides at am...

Sterically bulky thioureas as air- and moisture-stable ligands for pd-catalyzed Heck reactions of aryl halides.

Org. Lett. 6 , 1577, (2004)

We demonstrate that sterically bulky N,N'-disubstituted cyclic thiourea-Pd(0) complexes are air- and moisture-stable and highly active catalysts for palladium-catalyzed Heck reaction of aryl iodides a...