1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene

Names

[ Name ]:
1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene

[Synonym ]:
Q-PHOS
1-[Bis(2-methyl-2-propanyl)phosphino]-1',2',3',4',5'-pentaphenylferrocene
1,2,3,4,5-Pentaphenyl-1′-(di-tert-butylphosphino)ferrocene
Ferrocene, 1-[bis(1,1-dimethylethyl)phosphino]-1',2',3',4',5'-pentaphenyl-
MFCD03788940
1,2,3,4,5-pentaphenyl-1'-di-tert-butylphosphinoferrocene
CTC-Q-PHOS

Chemical & Physical Properties

[ Melting Point ]:
211-219ºC

[ Molecular Formula ]:
C₄₈H₄₇FeP

[ Molecular Weight ]:
710.706

[ Exact Mass ]:
710.276489

[ PSA ]:
13.59000

[ LogP ]:
11.36320

[ Appearance of Characters ]:
Powder | pink

[ Water Solubility ]:
Soluble in ether, benzene, toluene and terahydrofuran.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions.

J. Am. Chem. Soc. 128 , 4976, (2006)

The intermolecular alpha-arylation and vinylation of amides by palladium-catalyzed coupling of aryl bromides and vinyl bromides with zinc enolates of amides is reported. Reactions of three different t...