White catalyst

Names

[ Name ]:
White catalyst

[Synonym ]:
White catalyst
Benzene, 1,1'-(1,2-ethanediyldisulfinyl)bis-, palladium(2+) salt, compd. with acetic acid (1:1:2)
Palladium(2+) acetate 1,1'-(1,2-ethanediyldisulfinyl)dibenzene (1:2:1)
1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate

Chemical & Physical Properties

[ Molecular Formula ]:
C₁₈H₂₀O₆PdS₂

[ Molecular Weight ]:
502.898

[ Exact Mass ]:
501.973602

[ PSA ]:
125.16000

[ LogP ]:
4.36100

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
41

[ Safety Phrases ]:
26-39

[ RIDADR ]:
NONH for all modes of transport

Articles

syn-1,2-Amino alcohols via diastereoselective allylic C-H amination.

J. Am. Chem. Soc. 129 , 7274, (2007)

Macrolactonization via hydrocarbon oxidation.

J. Am. Chem. Soc. 128 , 9032, (2006)

A novel Pd/sulfoxide-catalyzed macrolactonization reaction of linear omega-alkenoic acids is reported that proceeds via serial ligand-catalyzed allylic C-H oxidation. The scope of this macrolactonizat...