(Isopropenyloxy)(trimethyl)silane

Names

[ Name ]:
(Isopropenyloxy)(trimethyl)silane

[Synonym ]:
Isopropenoxytrimethylsilane
Acetone enol trimethylsilyl ether
ISOPROPENYLOXYTRIMETHYLSILANE
IPOTMS
trimethylsilyl enol ether of acetone
Trimethyl(prop-1-en-2-yloxy)silane
Silane, (isopropenyloxy)trimethyl-
IsopropenyloxytriMethylsilane [TriMethylsilylating Agent]
MFCD00042845
Silane, trimethyl((1-methylethenyl)oxy)-
Silane, trimethyl[(1-methylethenyl)oxy]-
Trimethyl((1-methylvinyl)oxy)silane
EINECS 217-393-1
(Isopropenyloxy)(trimethyl)silane
Trimethyl Isopropenoxysilane

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
93.0±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₄OSi

[ Molecular Weight ]:
130.260

[ Flash Point ]:
7.2±0.0 °C

[ Exact Mass ]:
130.081390

[ PSA ]:
9.23000

[ LogP ]:
2.77

[ Vapour Pressure ]:
57.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.400

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26-S36

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2931900090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Concise total synthesis and stereochemical revision of (+)-naseseazines A and B: regioselective arylative dimerization of diketopiperazine alkaloids.

J. Am. Chem. Soc. 133 , 14940-14943, (2011)

Concise and enantioselective total syntheses of (+)-naseseazines A and B are described. Our regioselective and directed dimerization of diketopiperazines provides their critical C3-C(sp(2)) linkages, ...

Total synthesis of (+/-)-powelline and (+/-)-buphanidrine.

Org. Lett. 12(6) , 1252-4, (2010)

The total synthesis of (+/-)-powelline (13 linear steps in an overall yield of 6%) and (+/-)-buphanidrine (14 linear steps and a 6% overall yield) and has been achieved using a novel approach to the c...

Organotin triflate as practical catalyst for Michael addition of enol silyl ethers. Sato T, et al.

Tetrahedron 47(47) , 9773-82, (1991)