4-Bromobenzyl cyanide
Names
[ CAS No. ]:
16532-79-9
[ Name ]:
4-Bromobenzyl cyanide
[Synonym ]:
4-Bromobenzyl cyanide
EINECS 240-602-2
MFCD00001916
2-(4-bromophenyl)acetonitrile
(4-Bromophenyl)acetonitrile
4-bromophenylacetonitrile
Benzeneacetonitrile, 4-bromo-
4-Bromo phenylacetonitrile
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
286.2±15.0 °C at 760 mmHg
[ Melting Point ]:
47-49 °C(lit.)
[ Molecular Formula ]:
C8H6BrN
[ Molecular Weight ]:
196.044
[ Flash Point ]:
126.9±20.4 °C
[ Exact Mass ]:
194.968353
[ PSA ]:
23.79000
[ LogP ]:
2.22
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.573
[ Water Solubility ]:
slightly soluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- AL8090000
- CHEMICAL NAME :
- Acetonitrile, (p-bromophenyl)-
- CAS REGISTRY NUMBER :
- 16532-79-9
- BEILSTEIN REFERENCE NO. :
- 1861069
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C8-H6-Br-N
- MOLECULAR WEIGHT :
- 196.06
- WISWESSER LINE NOTATION :
- NC1R DE
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 56 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03252
Safety Information
[ Symbol ]:
GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H312 + H332-H315-H319-H335
[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R20/21/22;R36/37/38
[ Safety Phrases ]:
S26-S36/37/39-S38-S26/36/37/39
[ RIDADR ]:
3276
[ WGK Germany ]:
3
[ RTECS ]:
AL8090000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
2926909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2926909090
[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Chem. Commun. (Camb.) (20) , 2632-3, (2003)
Bright (maximum 10034 cd m(-2), 455 cd m(-2) at 20 mA cm(-2)) and efficient (maximum 2.4% at 4 mA cm(-2)) red (lambda(max)el 634-636 nm) organic light-emitting diodes employ arylamino-substituted fuma...
A mild and efficient method for the reduction of nitriles. Laval S, et al.Tetrahedron Lett. 50(50) , 7005-7007, (2009)
Polymeric light emitting properties and structural relationships of fluorene-based conjugated copolymers containing various hole transporting derivatives. Park JH, et al.
Org. Electron. 8(2) , 272-285, (2007)