Tosyl cyanide

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
289.8±0.0 °C at 760 mmHg

[ Melting Point ]:
47-50 °C(lit.)

[ Molecular Formula ]:
C₈H₇NO₂S

[ Molecular Weight ]:
181.212

[ Flash Point ]:
125.5±21.5 °C

[ Exact Mass ]:
181.019745

[ PSA ]:
66.31000

[ LogP ]:
1.28

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.548

[ Storage condition ]:
2-8°C

Click to get detail MSDS

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H312 + H332-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R20/21;R34

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2926909090

Precursor

DownStream

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.

J. Org. Chem. 68(21) , 8256-7, (2003)

The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield...

Radical-mediated alkenylation, alkynylation, methanimination, and cyanation of B-alkylcatecholboranes.

Angew. Chem. Int. Ed. Engl. 45 , 5847, (2006)

Synthesis , 2551, (2006)

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