4-Bromobenzyl bromide

Names

[ CAS No. ]:
589-15-1

[ Name ]:
4-Bromobenzyl bromide

[Synonym ]:
p-Bromobenzyl-bromide
Benzene, 1-bromo-4- (bromomethyl)-
Benzene, 1-bromo-4-(bromomethyl)-
EINECS 209-636-5
4-Bromobenzyl bromide
MFCD00000179
Toluene, p,α-dibromo-
1-Bromo-4-(bromomethyl)benzene
α,p-Dibromotoluene

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
258.2±15.0 °C at 760 mmHg

[ Melting Point ]:
62-64 °C(lit.)

[ Molecular Formula ]:
C₇H₆Br₂

[ Molecular Weight ]:
249.930

[ Flash Point ]:
122.2±19.6 °C

[ Exact Mass ]:
247.883606

[ LogP ]:
3.69

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.606

[ Storage condition ]:
Store at R.T.

[ Water Solubility ]:
MAY DECOMPOSE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H334

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S22-S26-S36/37/39-S45-S25

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29036990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Solution-phase synthesis of an aminomethyl-substituted biaryl library via sequential amine N-alkylation and Suzuki cross-coupling.

J. Comb. Chem. 3(5) , 473-6, (2001)

Described herein is the semiautomated preparation of a 20-member aminomethyl-substituted biaryl library. The two-step solution-phase synthesis was achieved via sequential N-alkylation of various amine...

Occupational hazard evaluation of p-bromobenzyl bromide from tests for genotoxicity.

Drug Chem. Toxicol. 22(4) , 583-93, (1999)

As part of an occupational hazard evaluation, p-bromobenzyl bromide (p-BBB) was evaluated for genotoxic activity in the Ames microbial mutagenicity assay, the alkaline elution assay for DNA strand bre...