Gold(1+) chloride-triphenylphosphine (1:1:1)
Names
[ CAS No. ]:
14243-64-2
[ Name ]:
Gold(1+) chloride-triphenylphosphine (1:1:1)
[Synonym ]:
Phosphine, triphenyl-, gold(1+) salt, hydrochloride (1:1:1)
Gold(1+) chloride - triphenylphosphine (1:1:1)
(Triphenylphosphine)gold(I) Chloride
EINECS 238-117-6
Chloro(triphenylphosphine)gold
(Ph3P)AuCl (Triphenylphosphinegold(I) chloride
MFCD00009588
chlorogold,triphenylphosphane
Biological Activity
[Description]:
[Related Catalog]:
Chemical & Physical Properties
[ Boiling Point ]:
360ºC at 760 mmHg
[ Melting Point ]:
248-249°C
[ Molecular Formula ]:
C18H15AuClP
[ Molecular Weight ]:
494.71
[ Flash Point ]:
181.7ºC
[ Exact Mass ]:
494.026489
[ PSA ]:
13.59000
[ LogP ]:
4.13180
[ Vapour Pressure ]:
4.74E-05mmHg at 25°C
[ Storage condition ]:
Store under Nitrogen
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36/37/39-S37/39
[ RIDADR ]:
NONH for all modes of transport
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Biol. Inorg. Chem. 11(5) , 559-70, (2006)
Electrospray ionisation (ESI) mass spectrometry was used to examine the reactions of the clinically used antiarthritic agent [Au(S2O3)2]3-, and AuPEt3Cl, a derivative of another clinically used agent ...
Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via Huisgen cycloaddition studies.J. Org. Chem. 78(3) , 920-34, (2013)
A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles directly from oximes and alkynes was developed via independent optimization of two key steps of the proces...
A powerful chiral counterion strategy for asymmetric transition metal catalysis.Science 317 , 496-499, (2007)
Traditionally, transition metal-catalyzed enantioselective transformations rely on chiral ligands tightly bound to the metal to induce asymmetric product distributions. Here we report high enantiosele...