Isopropenyl acetate
Names
[ CAS No. ]:
108-22-5
[ Name ]:
Isopropenyl acetate
[Synonym ]:
1-methylethenyl acetate
ACETONE ENOL ACETATE
2-acetyloxy-1-propene
1-PROPEN-2-OL ACETATE
MFCD00008709
1-Propen-2-yl acetate
2-acetoxy-1-propene
Prop-1-en-2-yl acetate
1-Methylvinyl acetate
2-Acetoxypropylene
2-propen-2-yl acetate
1-Propen-2-ol, acetate
Isopropenyl acetate
EINECS 203-562-7
Propen-2-yl acetate
isopropernyl acetate
i-propenyl acetate
ISO-RPOPENYL ACETATE
2-Acetoxypropene
Acetic Acid Isopropenyl Ester
2-propenyl acetate
Chemical & Physical Properties
[ Density]:
0.9±0.1 g/cm3
[ Boiling Point ]:
97.0±0.0 °C at 760 mmHg
[ Melting Point ]:
-93 °C
[ Molecular Formula ]:
C5H8O2
[ Molecular Weight ]:
100.116
[ Flash Point ]:
18.9±0.0 °C
[ Exact Mass ]:
100.052429
[ PSA ]:
26.30000
[ LogP ]:
1.28
[ Vapour Pressure ]:
42.5±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.400
[ Water Solubility ]:
34 g/L (20 ºC)
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UD4200000
- CHEMICAL NAME :
- 1-Propen-2-ol, acetate
- CAS REGISTRY NUMBER :
- 108-22-5
- BEILSTEIN REFERENCE NO. :
- 1280347
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 6
- MOLECULAR FORMULA :
- C5-H8-O2
- MOLECULAR WEIGHT :
- 100.13
- WISWESSER LINE NOTATION :
- 1VOY1&U1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,355,1986
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- AJOPAA American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- 1918- Volume(issue)/page/year: 29,1363,1946
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,355,1986 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 20 mg/m3 JAN 1993
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H335
[ Precautionary Statements ]:
P210-P304 + P340 + P312-P403 + P235
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
S9-S16-S29-S33
[ RIDADR ]:
UN 2403 3/PG 2
[ WGK Germany ]:
1
[ RTECS ]:
UD4200000
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2942000000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915390090
[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%
Articles
J. Appl. Polym. Sci. 86(3) , 639-646, (2002)
Reactions of isopropenyl acetate. Hagemeyer HJ and Hull DC.
Ind. and Eng. Chem. 41(12) , 2920-2924, (1949)
Molecular iodine in isopropenyl acetate (IPA): a highly efficient catalyst for the acetylation of alcohols, amines and phenols under solvent free conditions. Ahmed N and van Lier JE.
Tetrahedron Lett. 47(30) , 5345-5349, (2006)