Alkaline hydrolysis of tertiary N-(2-pyridyl) carbamates. Contradictory evidence between nucleophilic and general base catalysis
D Silva, F Norberto, S Santos, P Hervés
Index: Silva, Daniel; Norberto, Fatima; Santos, Susana; Herves, Pablo Journal of Physical Organic Chemistry, 2009 , vol. 22, # 3 p. 221 - 228
Full Text: HTML
Citation Number: 0
Abstract
Abstract The mechanism of the alkaline hydrolysis of phenyl N-methyl-N-(2-pyridyl) carbamate was investigated in order to evaluate the type of catalysis involved. The kinetic solvent isotope effect, the α-effect for the hydrolysis in peroxymonocarbonate ion, the
Related Articles:
Chloroformate Free, Scalable Approach for the Synthesis of Organic Carbamates and Their Alkylation
[Shewalkar, Mukesh P.; Rao, Ramakrishna R.; Reddy, Veerbhadra; Darandale, Sunil N.; Shinde, Devanand B. Letters in Organic Chemistry, 2013 , vol. 10, # 1 p. 60 - 64]
[Londregan, Allyn T.; Jennings, Sandra; Wei, Liuqing Organic Letters, 2010 , vol. 12, # 22 p. 5254 - 5257]
[Bernardi, Paolo; Dembech, Pasquale; Fabbri, Gaia; Ricci, Alfredo; Seconi, Giancarlo Journal of Organic Chemistry, 1999 , vol. 64, # 2 p. 641 - 643]
A convenient synthesis of 2-(alkylamino) pyridines
[Krein, Douglas M.; Lowary, Todd L. Journal of Organic Chemistry, 2002 , vol. 67, # 14 p. 4965 - 4967]
A Highly Versatile Catalyst System for the Cross??Coupling of Aryl Chlorides and Amines
[Lundgren, Rylan J.; Sappong-Kumankumah, Antonia; Stradiotto, Mark Chemistry - A European Journal, 2010 , vol. 16, # 6 p. 1983 - 1991]