A Highly Versatile Catalyst System for the Cross??Coupling of Aryl Chlorides and Amines

…, A Sappong??Kumankumah…

Index: Lundgren, Rylan J.; Sappong-Kumankumah, Antonia; Stradiotto, Mark Chemistry - A European Journal, 2010 , vol. 16, # 6 p. 1983 - 1991

Full Text: HTML

Citation Number: 118

Abstract

Abstract The syntheses of 2-(di-tert-butylphosphino)-N, N-dimethylaniline (L1, 71%) and 2- (di-1-adamantylphosphino)-N, N-dimethylaniline (L2, 74%), and their application in Buchwald–Hartwig amination, are reported. In combination with [Pd (allyl) Cl] 2 or [Pd (cinnamyl) Cl] 2, these structurally simple and air-stable P, N ligands enable the cross- coupling of aryl and heteroaryl chlorides, including those bearing as substituents ...

Related Articles:

Chloroformate Free, Scalable Approach for the Synthesis of Organic Carbamates and Their Alkylation

[Shewalkar, Mukesh P.; Rao, Ramakrishna R.; Reddy, Veerbhadra; Darandale, Sunil N.; Shinde, Devanand B. Letters in Organic Chemistry, 2013 , vol. 10, # 1 p. 60 - 64]

Palladium-Catalyzed C8-Selective C–H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric, and Solvation Effects on the Site Selectivity by Mechanistic …

[Londregan, Allyn T.; Jennings, Sandra; Wei, Liuqing Organic Letters, 2010 , vol. 12, # 22 p. 5254 - 5257]

A general and convenient procedure for the synthesis of N-alkylarylamines and N-alkylheteroarylamines by electrophilic amination of cuprates with N- …

[Bernardi, Paolo; Dembech, Pasquale; Fabbri, Gaia; Ricci, Alfredo; Seconi, Giancarlo Journal of Organic Chemistry, 1999 , vol. 64, # 2 p. 641 - 643]

A convenient synthesis of 2-(alkylamino) pyridines

[Krein, Douglas M.; Lowary, Todd L. Journal of Organic Chemistry, 2002 , vol. 67, # 14 p. 4965 - 4967]

Ruthenium complex-controlled catalytic N-mono-or N, N-dialkylation of heteroaromatic amines with alcohols

[Watanabe, Yoshihisa; Morisaki, Yasuhiro; Kondo, Teruyuki; Mitsudo, Take-Aki Journal of Organic Chemistry, 1996 , vol. 61, # 13 p. 4214 - 4218]

More Articles...