Preparation of Thiol Acids, Thiol Esters and Amides by Reactions of Carbonyl Sulfide with Grignard Reagents
AR Katritzky, JL Moutou, Z Yang
Index: Katritzky, Alan R.; Moutou, Jean-Luc; Yang, Zhijun Organic Preparations and Procedures International, 1995 , vol. 27, # 3 p. 361 - 366
Full Text: HTML
Citation Number: 2
Abstract
Reactions of Grignard reagents with carbon dioxide are well documented in the literature, and provide a general method for the preparation of carboxylic acids. 1.2 Similarly, dithiocarboxylic acids and esters have been prepared from carbon disulfide. 3 Grignard reagents were reported to react with carbonyl sulfide affording mixtures of thiol acids (9- 73%) and tertiary alcohols (22-52%) in ratios which depend on the Grignard reagent used! ...
Related Articles:
Solvent free, N, N′-carbonyldiimidazole (CDI) mediated amidation
[Verma, Sanjeev K.; Ghorpade, Ramarao; Pratap, Ajay; Kaushik Tetrahedron Letters, 2012 , vol. 53, # 19 p. 2373 - 2376]
[Fache, Fabienne; Bethmont, Valerie; Jacquot, Laurent; Lemaire, Marc Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands, 1996 , vol. 115, # 4 p. 231 - 238]
[Bailen, Miguel A; Chinchilla, Rafael; Dodsworth, David J; Najera, Carmen Tetrahedron Letters, 2002 , vol. 43, # 9 p. 1661 - 1664]
[Hosseini Sarvari, Mona; Sharghi, Hashem Tetrahedron, 2005 , vol. 61, # 46 p. 10903 - 10907]
[Hans, Jeremy J.; Driver, Russell W.; Burke, Steven D. Journal of Organic Chemistry, 2000 , vol. 65, # 7 p. 2114 - 2121]