Reaction of N-nitroso-and N-nitro-N-alkylamides with amines

J Garcia, J Gonzalez, R Segura, F Urpi…

Index: Garcia, Jordi; Gonzalez, Javier; Segura, Ramon; Urpi, Felix; Vilarrasa, Jaume Journal of Organic Chemistry, 1984 , vol. 49, # 18 p. 3322 - 3327

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Citation Number: 31

Abstract

Several N-nitroso-and N-nitrocarboxamides have been characterized by'H and'3c NMR spectroscopy. These compounds react with ammonia and aliphatic amines to afford mainly carboxamides of general formula RCONH2, RCONHR', or RCONR'R''. N- Nitrosocarboxamides and aromatic amines give poor yields of RCONHAr; by contrast, N- nitrocarboxamides and aromatic amines lead to RCONHAr in good yields. The higher ...

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