Continuous organomagnesium synthesis of organometallic compounds

PA Storozhenko, AA Grachev, AO Klochkov…

Index: Storozhenko; Grachev; Klochkov; Shiryaev Russian Journal of Applied Chemistry, 2013 , vol. 86, # 3 p. 387 - 393

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Abstract

Abstract Continuous organomagnesium synthesis of a number of organic derivatives of 14th group elements of the periodic table was examined in a column apparatus with an agitator. An effect of a molar ratio of reactants, temperature in a reaction zone, and other factors was studied on the yield and composition of the products.

~96%

~10%

~96%

~88%

~99%

REACTION OF TRIPHENYLTIN-LITHIUM WITH ORGANIC HALIDES

[Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.1, page 141 - 147 Full Text Show Details Gilman, H.; Rosenberg, S. D. Journal of Organic Chemistry, 1953 , vol. 18, p. 680 - 685]

Phenyltin compounds

[Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.1, page 141 - 147 Full Text Show Details Chambers, R. F.; Scherer, P. C. Journal of the American Chemical Society, 1926 , vol. 48, p. 1054 - 1062]

The preparation of organolithium compounds by the transmetal...

[Seyferth, D.; Weiner, M. A. Journal of the American Chemical Society, 1962 , vol. 84, p. 361 - 364]

Some Reactions of Triphenyltinlithium and Triphenylleadlithi...

[Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.1, page 141 - 147 Full Text Show Details Gilman, H.; Marrs, O. L.; Sim, S. Y. Journal of Organic Chemistry, 1962 , vol. 27, p. 4232 - 4236]