Russian journal of general chemistry

Hydroamination of carbonyl compounds with oximes

VA Tarasevich, NG Kozlov

Index: Tarasevich; Kozlov Russian Journal of General Chemistry, 2004 , vol. 74, # 3 p. 379 - 383

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Citation Number: 2

Abstract

In the present work we report on a new catalytic method of synthesis of N-alkylated benzylamines and (1-phenylethyl)amines by hydroamination of aliphatic aldehydes and ketones with benzaldehyde, p-fluoro- benzaldehyde, acetophenone, and p-acetophenone oximes. The method is based on the earlier developed procedure of hydroamination of aliphatic aldehydes with benzaldehyde oxime [2] and involves passing of the aldehyde and oxime in a (1.231.5):1 molar ratio ...