Journal of fluorine chemistry

Reaction of bis (trifluoromethyl) amino-oxyl with alkylchlorosilanes and allyldichloro (methyl) silane and of perfluoro-2, 5-diazahexane 2, 5-dioxyl with vinylsilanes and …

AE Tipping, RB Yadav

Index: Tipping, Anthony E.; Yadav, Rajendraprasad B. Journal of Fluorine Chemistry, 1994 , vol. 68, # 1 p. 1 - 10

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Abstract

Abstract Treatment of the silanes MeSiHCl 2, Me 2 SiHCl and EtSiMeCl 2 with the oxyl (CF 3) 2 NO·(1) gives the substitution products (CF 3) 2 NOSiMeCl 2 (4) and (CF 3) 2 NOSiMe 2 Cl (5), and a mixture of (CF 3) 2 NOCHMeSiMeCl 2 (8) and (CF 3) 2 NOCH 2 CH 2 SiMeCl 2 (9)(ratio 20: 37), respectively, while the silane EtSiMe 2 Cl affords mainly the ester (CF 3) 2 NO 2 CMe (7). Attack of oxyl 1 on the silane CH 2= CHCH2SiMeCl 2 results in both allylic ...