Journal of fluorine chemistry

Generation of 15N labelled bis (polyfluoroalkyl) nitroxides and their hydrogen-abstraction reactions with alkanes, alkylbenzenes and aldehydes

CX Zhao, GF Chen, XK Jiang

Index: Zhao, Cheng-Xue; Chen, Guo-Fei; Jiang, Xi-Kui Journal of Fluorine Chemistry, 1988 , vol. 38, p. 391 - 398

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Citation Number: 7

Abstract

Abstract Blue solutions containing 15 labelled bis (polyfluoralkyl) nitroxides and spin traps, polyfluoronitrosoalkanes, were conveniently made from the reactions of Na 15 NO 2 with polyfluoro-compounds,(RF CO 2) and RF SO 2 Br in F113. It has been found that the nitroxides effected fast H-abstraction from alkanes, alkylbenzenes, aldehydes and the radicals derived from the substrates were in turn effectively trapped by RF 15 NO to give ...