Chemical Communications 2006-01-28

Nickel-catalyzed coupling of allyl chlorides and enynes.

Shin-ichi Ikeda, Kaori Suzuki, Kazunori Odashima

Index: Chem. Commun. (Camb.) (4) , 457-9, (2006)

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Abstract

The Ni-catalyzed coupling of allyl chlorides and enynes has been developed; the cyclization of enynes was triggered by the addition of pi-allylnickel species to the alkyne part, followed by the incorporation of the alkene part.