Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts

T Mitsudome, A Noujima, T Mizugaki…

Index: Mitsudome, Takato; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi Chemical Communications, 2012 , vol. 48, # 96 p. 11733 - 11735

Full Text: HTML

Citation Number: 8

Abstract

Hydrotalcite-supported gold nanoparticles (Au/HT) catalyzed the highly efficient double- carbonylation of amines to oxamides under mild reaction conditions. Various amines were selectively converted to the corresponding oxamides. The cooperation between gold nanoparticles and basic sites of HT plays a key role in the reaction.

 Related Synthetic Route
carbon monoxide Structure

201230-82-2

carbon monoxide

Benzylamine Structure

100-46-9

Benzylamine

~48%

Benzenemethanamine,N-(phenylmethylene)- Structure

780-25-6

Benzenemethanam...

carbon monoxide Structure

201230-82-2

carbon monoxide

Dimethylamine Structure

124-40-3

Dimethylamine

~72%

N,N,N',N'-tetramethyloxamide Structure

1608-14-6

N,N,N',N'-tetra...

Hexylamine Structure

111-26-2

Hexylamine

carbon monoxide Structure

201230-82-2

carbon monoxide

~43%

N-hexylhexan-1-imine Structure

34695-21-1

N-hexylhexan-1-imine

morpholine Structure

110-91-8

morpholine

carbon monoxide Structure

201230-82-2

carbon monoxide

~93%

1,2-dimorpholin-4-ylethane-1,2-dione Structure

6342-79-6

1,2-dimorpholin...

carbon monoxide Structure

201230-82-2

carbon monoxide

Diethylamine Structure

109-89-7

Diethylamine

~89%

N,N,N',N'-tetraethyloxamide Structure

14288-05-2

N,N,N',N'-tetra...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved