Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts

T Mitsudome, A Noujima, T Mizugaki…

文献索引：Mitsudome, Takato; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi Chemical Communications, 2012 , vol. 48, # 96 p. 11733 - 11735

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被引用次数: 8

摘要

Hydrotalcite-supported gold nanoparticles (Au/HT) catalyzed the highly efficient double- carbonylation of amines to oxamides under mild reaction conditions. Various amines were selectively converted to the corresponding oxamides. The cooperation between gold nanoparticles and basic sites of HT plays a key role in the reaction.