Strongly phosphorescent palladium (II) complexes of tetradentate ligands with mixed oxygen, carbon, and nitrogen donor atoms: photophysics, photochemistry, and …

…, GSM Tong, SL Lai, SCF Kui, WM Kwok…

Index: Chow, Pui Keong; Ma, Chensheng; To, Wai-Pong; Tong, Glenna So Ming; Lai, Shiu-Lun; Kui, Steven C. F.; Kwok, Wai-Ming; Che, Chi-Ming Angewandte Chemie - International Edition, 2013 , vol. 52, # 45 p. 11775 - 11779 Angew. Chem., 2013 , vol. 125, # 45 p. 11991 - 11995

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Citation Number: 23

Abstract

Transition-metal complexes that show strong phosphorescence in solution at room temperature usually contain a RuII, OsII, IrIII, or PtII ion, but luminescent AuIII complexes [1] have also been studied increasingly. In contrast to the extensive literature on luminescent PtII complexes,[2] examples of luminescent PdII complexes that contain non-porphyrin ligands and show decent emission quantum yields (Fem) are sparse.[3] The crux of this ...