Transacylation of α-Aryl-β-keto Esters

…, F Hidaka, S Shimizu, M Tamura, K Hori…

Index: Nishiwaki, Nagatoshi; Nishida, Daisei; Ohnishi, Tetsuya; Hidaka, Fumie; Shimizu, Satoru; Tamura, Mina; Hori, Kazushige; Tohda, Yasuo; Ariga, Masahiro Journal of Organic Chemistry, 2003 , vol. 68, # 22 p. 8650 - 8656

Full Text: HTML

Citation Number: 20

Abstract

The acyl group of an α-aryl-β-keto ester was readily transferred to N-, O-, and S- nucleophiles. The transacylation from arylated diethyl 3-oxoglutarate to amines led to unsymmetrical malonic acid amide esters in high yields. The present reaction proceeded under mild conditions without formation of detectable byproducts. Only simple experimental manipulations were required. This reaction was also found to be sensitive to steric factors, ...

~89%

~95%

~98%

~76%

~0%

~0%

~0%

~0%

~0%

~92%

~0%

~0%

~0%

~0%

~0%

~0%

~64%

~98%

~75%

~99%

Carbonylation of quaternary ammonium salts to tertiary amide...

[Lei, Yizhu; Zhang, Rui; Wu, Qing; Mei, Hui; Xiao, Bo; Li, Guangxing Journal of Molecular Catalysis A: Chemical, 2014 , vol. 381, p. 120 - 125]

Poly-(N, N′-dibromo-N-ethyl-benzene-1, 3-disulfonamide) and ...

[Veisi, Hojat; Ghorbani-Vaghei, Ramin; Eskandari, Hosna; Hemmati, Saba; Rezaei, Ardashir; Hajinazari, Somaye; Far, Mohammad Raoof Heidari; Entezari, Azam Phosphorus, Sulfur and Silicon and the Related Elements, 2011 , vol. 186, # 2 p. 213 - 219]

Ruthenium (III) acetylacetonate [Ru (acac) 3]-an efficient r...

[Varala, Ravi; Nasreen, Aayesha; Adapa, Srinivas R. Canadian Journal of Chemistry, 2007 , vol. 85, # 2 p. 148 - 152]

Ruthenium-catalyzed reaction of carbon dioxide, amine, and a...

[Journal of Organic Chemistry, , vol. 52, # 19 p. 4389 - 4391]

Immobilization of Candida cylindracea lipase on poly lactic ...

[Badgujar, Kirtikumar C.; Dhake, Kishor P.; Bhanage, Bhalchandra M. Process Biochemistry, 2013 , vol. 48, # 9 p. 1335 - 1347]