4-Fluoroanilines: synthesis and decomposition

A Zakrzewska, E Kolehmainen, B Osmialowski…

Index: Zakrzewska; Kolehmainen; Osmialowski; Gawinecki Journal of Fluorine Chemistry, 2001 , vol. 111, # 1 p. 1 - 10

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Citation Number: 22

Abstract

Fourteen N-and/or 2-substituted 4-fluoroanilines were prepared (the series includes N–C2- bridged compounds). Some of them were found to be thermally unstable when dissolved in chloroform. Both 19F NMR spectra and comparison of GIAO-DFT calculated and experimental 13C chemical shifts were used to suggest decomposition products of 4- fluoroanilines.