4-Fluoro-2-methylaniline

Modify Date: 2025-08-26 11:49:17

4-Fluoro-2-methylaniline Structure
4-Fluoro-2-methylaniline structure
 Common Name 4-Fluoro-2-methylaniline
CAS Number 452-71-1 Molecular Weight 125.144
Density 1.1±0.1 g/cm3 Boiling Point 206.9±20.0 °C at 760 mmHg
Molecular Formula C7H8FN Melting Point 14ºC
MSDS Chinese USA Flash Point 87.8±0.0 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 4-Fluoro-2-methylaniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 206.9±20.0 °C at 760 mmHg
Melting Point 14ºC
Molecular Formula C7H8FN
Molecular Weight 125.144
Flash Point 87.8±0.0 °C
Exact Mass 125.064079
PSA 26.02000
LogP 1.61
Vapour Pressure 0.2±0.4 mmHg at 25°C
Index of Refraction 1.542
Storage condition Room temperature.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CY0500000
CHEMICAL NAME :
Benzenamine, 4-fluoro-2-methyl-
CAS REGISTRY NUMBER :
452-71-1
BEILSTEIN REFERENCE NO. :
1931798
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H8-F-N
MOLECULAR WEIGHT :
125.16
WISWESSER LINE NOTATION :
ZR DF B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
2 umol/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 77,317,1980

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302 + H312 + H332-H315-H319-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic;
Risk Phrases R23/24/25;R36/37/38
Safety Phrases S26-S36/37/39-S45
RIDADR 2810
WGK Germany 3
RTECS CY0500000
Packaging Group III
Hazard Class 6.1

 Synthetic Route

5-Fluoro-2-nitrotoluene structure

5-Fluoro-2-nitr...

CAS#:446-33-3

~97%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: Polivka; Jilek; Holubek; et al. Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 1 p. 86 - 109
N-(4-fluoro-2-methylphenyl)-2-methylpropane-2-sulfinamide structure

N-(4-fluoro-2-m...

CAS#:1338209-86-1

~93%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: Prakash, Anjanappa; Dibakar, Mullick; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5625 - 5628
3-Fluorotoluene structure

3-Fluorotoluene

CAS#:352-70-5

5-Fluoro-2-nitrotoluene structure

5-Fluoro-2-nitr...

CAS#:446-33-3

~%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: E. I. Du Pont de Nemours and Company Patent: US4146625 A1, 1979 ;
Methyl fluoride structure

Methyl fluoride

CAS#:593-53-3

4-Fluoroaniline structure

4-Fluoroaniline

CAS#:371-40-4

~90%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: Attina, Marina; Cacace, Fulvio; de Petris, Giulia Journal of the American Chemical Society, 1985 , vol. 107, p. 1556 - 1561
2-Nitrotoluene structure

2-Nitrotoluene

CAS#:88-72-2

~49%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

o-Toluidine structure

o-Toluidine

CAS#:95-53-4

Literature: Tordeux, Marc; Wakselman, Claude Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 251 - 254
3-Fluorotoluene structure

3-Fluorotoluene

CAS#:352-70-5

~%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: Tomcufcik,A.S.; Seeger,D.R. Journal of Organic Chemistry, 1961 , vol. 26, p. 3351 - 3356
2-Chloro-5-fluorotoluene structure

2-Chloro-5-fluo...

CAS#:33406-96-1

~%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: Prakash, Anjanappa; Dibakar, Mullick; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5625 - 5628
1-(4-fluoro-2-methyl-phenyl)-ethanone oxime structure

1-(4-fluoro-2-m...

CAS#:392-03-0

~%

4-Fluoro-2-methylaniline Structure

4-Fluoro-2-meth...

CAS#:452-71-1

Literature: Buu-Hoi; Xuong Journal of the Chemical Society, 1953 , p. 386

 Articles1

More Articles
SYNTHESIS OF SCHIFF BASES OF 7-METHOXY-2-[4-(METHYLSULFANYL) PHENYL]-1-BENZOFURAN-5-CARBOXALDEHYDE AND ANIMES AND HYDRAZIDE. Thorat BR, et al.

Heterocycl. Lett. 4(1) , 41-53, (2014)

 Synonyms

4-F-2-MePhNH2
2-Amino-5-fluorotoluene
3-FLUORO-6-AMINOTOLUENE
2-Fluoro-o-toluidine
4-Fluoro-2-methylani
ZR DF B1
2-Methyl-4-fluoroaniline
Benzenamine, 4-fluoro-2-methyl-
6-Amino-3-fluorotoluene
EINECS 207-208-2
MFCD00007832
4-Fluoro-2-methylaniline
4-fluorotoluidine
o-Toluidine,4-fluoro
4-fluoro-2-methylphenylamine
4-Fluoro-2-methylbenzenamine
4-Fluoro-o-toluidine
2-amino-5-fluorotoluen
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