Preparation and some reactions of thioacyl diphenylthiophosphinoyl and thioacyl diphenylphosphino sulfides

…, R Hattori, K Nishiwaki, M Mizuta, M Ishida

Index: Kato, Shinzi; Goto, Masahisa; Hattori, Rikizoh; Nishiwaki, Koh-ichi; Mizuta, Masateru; Ishida, Masaru Chemische Berichte, 1985 , vol. 118, # 4 p. 1668 - 1683

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Abstract

Abstract The reaction of sodium or caesium dithiocarboxylates with diphenylthiophosphinic and diphenylselenophosphinic chlorides gives purple thioacyl diphenylthiophosphinoyl 5 and dark green thioacyl diphenylselenophosphinoyl sulfides 6, which are useful thioacylating reagents under mild reaction conditions. Thioacyl diphenylphosphino sulfides 22, which can be obtained by the similar method using diphenylphosphinous chlorides, ...

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Phosphinothioicchloride, P,P-diphenyl Structure

1015-37-8

Phosphinothioic...

~%

methylsulfanyl-diphenyl-sulfanylidene-λ5-phosphane Structure

15288-70-7

methylsulfanyl-...

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N/A Structure

97270-52-5

N/A

~%

methylsulfanyl-diphenyl-sulfanylidene-λ5-phosphane Structure

15288-70-7

methylsulfanyl-...

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Natriumdiphenylphosphinodithioformiat Structure

5827-17-8

Natriumdiphenyl...

methyl iodide Structure

74-88-4

methyl iodide

~%

methylsulfanyl-diphenyl-sulfanylidene-λ5-phosphane Structure

15288-70-7

methylsulfanyl-...

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sodium 4-(methyl)dithiobenzoate Structure

53724-36-0

sodium 4-(methy...

~%

4-methyl-N-phenylbenzenecarbothioamide Structure

20199-06-8

4-methyl-N-phen...

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piperidinium 4-methylbenzenecarbodithiolate Structure

42967-76-0

piperidinium 4-...

~%

4-methyl-N-phenylbenzenecarbothioamide Structure

20199-06-8

4-methyl-N-phen...

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N/A Structure

97270-47-8

N/A

~%

4-methyl-N-phenylbenzenecarbothioamide Structure

20199-06-8

4-methyl-N-phen...

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N/A Structure

97270-52-5

N/A

~75%

ethyl 4-methylbenzenecarbodithioate Structure

63385-22-8

ethyl 4-methylb...

N/A Structure

97270-43-4

N/A

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Lithium thioethoxide Structure

30383-01-8

Lithium thioethoxide

N/A Structure

97270-52-5

N/A

~72%

ethyl 4-methylbenzenecarbodithioate Structure

63385-22-8

ethyl 4-methylb...

N/A Structure

97270-43-4

N/A

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Sodium benzeneselenolate Structure

23974-72-3

Sodium benzenes...

~80%

Diphenyldiselenide Structure

1666-13-3

Diphenyldiselenide

sodium 4-(methyl)dithiobenzoate Structure

53724-36-0

sodium 4-(methy...

Natriumdiphenylphosphinodithioformiat Structure

5827-17-8

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N-chlorosuccinimide Structure

128-09-6

N-chlorosuccinimide

N/A Structure

97270-46-7

N/A

~0%

di-(Thiobenzoyl) disulfide Structure

5873-93-8

di-(Thiobenzoyl...

N-(thiobenzoylthio)succinimide Structure

80031-12-5

N-(thiobenzoylt...

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N/A Structure

97270-52-5

N/A

~18%

N/A Structure

74670-37-4

N/A

N/A Structure

97270-44-5

N/A

N/A Structure

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N/A

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Methanol Structure

67-56-1

Methanol

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97270-47-8

N/A

~70%

methyl 4-methylbenzenecarbodithioate Structure

5977-87-7

methyl 4-methyl...

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piperidinium 4-methylbenzenecarbodithiolate Structure

42967-76-0

piperidinium 4-...

~%

methyl 4-methylbenzenecarbodithioate Structure

5977-87-7

methyl 4-methyl...

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N/A Structure

97270-47-8

N/A

~%

methyl 4-methylbenzenecarbodithioate Structure

5977-87-7

methyl 4-methyl...

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sodium 4-(methyl)dithiobenzoate Structure

53724-36-0

sodium 4-(methy...

methyl iodide Structure

74-88-4

methyl iodide

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methyl 4-methylbenzenecarbodithioate Structure

5977-87-7

methyl 4-methyl...

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METHYLLITHIUM Structure

917-54-4

METHYLLITHIUM

N/A Structure

97270-52-5

N/A

~18%

N/A Structure

74670-37-4

N/A

N/A Structure

97270-44-5

N/A

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DIETHYLAMINOTRIMETHYL TIN Structure

1068-74-2

DIETHYLAMINOTRI...

N/A Structure

97270-47-8

N/A

~17%

Tetraphenylbiphosphine Structure

1101-41-3

Tetraphenylbiph...

BIS(3,5-DIMETHYLPHENYL)DIETHYLAMINOPHOSPHINE Structure

1636-15-3

BIS(3,5-DIMETHY...

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Sodium benzenolate Structure

139-02-6

Sodium benzenolate

N/A Structure

97270-52-5

N/A

~82%

O-phenyl 4-methylbenzenecarbothioate Structure

52322-79-9

O-phenyl 4-meth...

N/A Structure

17534-85-9

N/A

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DIETHYLAMINOTRIMETHYL TIN Structure

1068-74-2

DIETHYLAMINOTRI...

N/A Structure

97270-47-8

N/A

~0%

Tetraphenylbiphosphine Structure

1101-41-3

Tetraphenylbiph...

BIS(3,5-DIMETHYLPHENYL)DIETHYLAMINOPHOSPHINE Structure

1636-15-3

BIS(3,5-DIMETHY...

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N-chlorosuccinimide Structure

128-09-6

N-chlorosuccinimide

N/A Structure

97270-46-7

N/A

~0%

di-(Thiobenzoyl) disulfide Structure

5873-93-8

di-(Thiobenzoyl...

N-(thiobenzoylthio)succinimide Structure

80031-12-5

N-(thiobenzoylt...

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N-chlorosuccinimide Structure

128-09-6

N-chlorosuccinimide

N/A Structure

97270-48-9

N/A

~0%

Disulfide, bis[(4-chlorophenyl)thioxomethyl] Structure

20710-50-3

Disulfide, bis[...

N-[4-(chloro)thiobenzoylthio]succinimide Structure

80031-14-7

N-[4-(chloro)th...

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N-chlorosuccinimide Structure

128-09-6

N-chlorosuccinimide

N/A Structure

97270-49-0

N/A

~0%

N/A Structure

20710-49-0

N/A

N-[4-(methoxy)thiobenzoylthio]succinimide Structure

80031-18-1

N-[4-(methoxy)t...

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