Acetylenic Ethers. I. Phenoxyacetylenes

TL Jacobs, R Cramer, FT Weiss

Index: Jacobs; Cramer; Weiss Journal of the American Chemical Society, 1940 , vol. 62, p. 1849,1854

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Citation Number: 11

Abstract

An equimolecular mixture of n-butyllithium and phenylmagnesium bromide gave a positive color test with Michler ketone, but no test with p-bromodimethylaniline. A 25-cc. aliquot of a 75-cc. ether solution containing 0 05 mole of n-butyllithium was shaken for one minute with 5 cc. of a-bromonaphthalene and there was obtained, subsequent to carbonation, 2.55 g.(87%) of a-naphthoic acid: To the remainder of the solution was added in one portion ...