Electrochemical and Spectroscopic Properties of Cyclometallated and Non??Cyclometallated Ruthenium (II) Complexes Containing Sterically Hindering Ligands of the …

…, R Kayhanian, P Gaviña, JP Sauvage

Index: Barigelletti, Francesco; Ventura, Barbara; Collin, Jean-Paul; Kayhanian, Robert; Gavina, Pablo; Sauvage, Jean-Pierre European Journal of Inorganic Chemistry, 2000 , # 1 p. 113 - 119

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Citation Number: 45

Abstract

Abstract Two series of cyclometallated and noncyclometallated ruthenium (II) complexes incorporating mono-or disubstituted 1, 10-phenanthroline-and 2, 2′: 6′, 2′′-terpyridine- type ligands have been synthesized and characterized. An X-ray crystal structure for one of the complexes, Ru (ttpy)(mapH)-(Cl)(PF 6), has been obtained (mapH= 2-p-anisyl-1, 10- phenanthroline; ttpy= 4′-tolyl-2, 2′: 6′, 2′′-terpyridine). Distinct electrochemical and ...