A novel transmetallation of arylzinc species into arylboronates from aryl halides in a barbier procedure

…, C Gosmini, JM Paris, J Perichon

Index: Claudel, Stephanie; Gosmini, Corinne; Paris, Jean Marc; Perichon, Jacques Chemical Communications, 2007 , # 35 p. 3667 - 3669

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Citation Number: 11

Abstract

During the course of our work, based on the cobalt-catalyzed formation of organometallic compounds, we have found a new method for the preparation of functionalized arylboronic esters from the corresponding arylzinc species. 8 Contrary to arylboronate esters, arylzinc species can neither be stored for a long time nor isolated because of their instability. Recently, we have established that arylzinc compounds 9 are convenient for the facile preparation of arylstannanes from ...